88388-83-4Relevant academic research and scientific papers
REACTIONS OF FLUORINE-CONTAINING FREE RADICALS IN SOLUTION.VI. REACTIVITY OF POLYFLUORINATED AROMATIC COMPOUNDS TOWARD TRIFLUOROMETHYL, 1,1-DIFLUOROETHYL, AND METHYL RADICALS
Komendantov, A. M.,Rondarev, D. S.,Sass, V. P.,Sokolov, S. A.
, p. 1684 - 1687 (2007/10/02)
The termal decomposition of fluoroalkanoyl peroxides in heptane at 50 deg C and of diacetyl peroxide in isooctane at 65 deg C was used as the source of the free radicals CF3., CH3CF2., and CH3..The ratio of the rate constants for abstraction of hydrogen from the solvent by the radical and the addition of the radical to hexafluorobenzene, octafluorotoluene, 1,4-bis(pentafluorophenoxy)perfluorobutane, 1,4-bis(trifluoromethyl)benzene, and benzene was determined.
