884865-77-4

Basic information

• Product Name: methyl N-(4-methylbenzenesulfonyl)phenylacetimidate
• Synonyms: methyl N-(4-methylbenzenesulfonyl)phenylacetimidate
• CAS NO: 884865-77-4
• Molecular Weight: 303.382
• Mol File: 884865-77-4.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: methyl N-(4-methylbenzenesulfonyl)phenylacetimidate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl N-(4-methylbenzenesulfonyl)phenylacetimidate(884865-77-4)
• EPA Substance Registry System: methyl N-(4-methylbenzenesulfonyl)phenylacetimidate(884865-77-4)

Safety Data

• Hazardous Substances Data: 884865-77-4(Hazardous Substances Data)

Upstream product

• 4369-00-0 (2,2,2-trimethoxyethyl)benzene 
• 70-55-3 toluene-4-sulfonamide 
• 39496-45-2 methyl imini ester hydrochloride of phenylacetic acid 
• 98-59-9 p-toluenesulfonyl chloride 
• 67-56-1 methanol 
• 924-44-7 glyoxylic acid ethyl ester 
• 941-55-9 4-toluenesulfonyl azide 
• 536-74-3 phenylacetylene 

Downstream Products

• 1273565-32-4 C₂₇H₂₇NO₅S 
• 4859-74-9 N¹-morpholinyl-N²-(4-methylbenzenesulfonyl)-2-phenylacetamidine 
• 884866-02-8 N¹-pyrrolidinyl-N²-(4-methylbenzenesulfonyl)-2-phenylacetamidine 

Relevant articles and documents

Highly Diastereoselective and Irreversible Aldol Reactions of N -Sulfonylimidates

A mild method for the aldolization of N-sulfonylimidates was developed. The reaction proceeds in excellent diastereoselectivity to provide a range of useful β-hydroxyimidates in high yield. The innate reversibility of the reaction is suppressed by the use of a titanium complex as a Lewis acid.

A new entry of copper-catalyzed four-component reaction: Facile access to α-Aryl β-hydroxy imidates

α-Aryl β-hydroxy imidates are efficiently obtained by the four-component reaction of ethyl glyoxylates, aryl acetylenes, sulfonyl azides, and alcohols using a copper catalyst. The developed procedure is characterized by high selectivity, mild reaction con