88549-79-5

Upstream product

• 88549-78-4 Toluene-4-sulfonate((4S,5R)-5-methyl-2-phenyl-4,5-dihydro-oxazol-4-ylmethyl)-triphenyl-phosphonium; 
• 107-02-8 acrolein 

Downstream Products

• 88549-82-0 (1R,3aR,4R,7aR)-1-((R)-1-Benzyloxy-ethyl)-3-oxo-2,3,3a,4,5,7a-hexahydro-1H-isoindole-4-carboxylic acid ethyl ester 
• 88549-81-9 Benzoic acid (Z)-(1R,2R)-2-((E)-3-ethoxycarbonyl-acryloylamino)-1-methyl-hexa-3,5-dienyl ester 
• 88549-80-8 Benzoic acid (Z)-(1R,2R)-2-amino-1-methyl-hexa-3,5-dienyl ester; hydrochloride 

Relevant academic research and scientific papers

HIGHLY STEREOSELECTIVE SYNTHESIS OF ANTITUMOR ANTIBIOTICS, (+)-ACTINOBOLIN AND (-)-BACTOBOLIN, BY ASYMMETRIC CYCLIZATION

A common skeleton of (+)-actinobolin and (-)-bactobolin was efficiently formed by an intramolecular Diels-Alder reaction of a chiral Z diene with a substituent at the pentadienylic carbon, and the following transformation completed the first total synthes