88635-94-3Relevant academic research and scientific papers
Highly diastereoselective addition of Et2AlCN to β-keto amides derived from (S)-4-isopropyl-2-oxazolidinone
Flores-Morales, Virginia,Fernandez-Zertuche, Mario,Ordonez, Mario
, p. 2693 - 2698 (2003)
The addition of Et2AlCN in the presence of ZnBr2 or Et2AlCl to 1,3-dicarbonyl compounds derived from (S)-4-isopropyl-2- oxazolidinone, proceeds with high diastereoselectivity (94-98% de) and good chemical yields. This type
Stereoselective synthesis of α-alkyl-β-keto imides via asymmetric redox C-C bond formation between α-alkyl-α-diazocarbonyl compounds and aldehydes
Hashimoto, Takuya,Miyamoto, Hisashi,Naganawa, Yuki,Maruoka, Keiji
supporting information; experimental part, p. 11280 - 11281 (2011/02/26)
(Chemical Equation Presented) Asymmetric redox C-C bond formation between α-alkyl-α-diazocarbonyl compounds and aldehydes was developed as a practical and general method for the construction of α-alkyl-β-keto imides having a chiral nonracemic tertiary ste
