88733-72-6Relevant academic research and scientific papers
ACYLATION REACTION OF HYDROXYL GROUP
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Page/Page column 15-16, (2010/07/03)
Disclosed is a selective ester production process of an alcoholic hydroxyl group, which proceeds under chemically mild conditions, while having adequate environmental suitability, operability and economical efficiency. Specifically disclosed is a process for producing an ester compound, which is characterized in that an alcohol and a carboxylic acid ester compound are reacted in the presence of a compound containing zinc element, thereby selectively acylating a hydroxyl group of the alcohol.
PALLADIUM-CATALYZED DOUBLE CARBONYLATION REACTIONS OF ARYL HALIDES AFFORDING α-KETO ESTERS
Ozawa, Fumiyuki,Kawasaki, Nobuo,Yamamoto, Takakazu,Yamamoto, Akio
, p. 567 - 570 (2007/10/02)
Various aryl iodides can be converted into α-keto esters in reactions with carbon monoxide and alcohols in the presence of tertiary amines and catalytic amounts of tertiary phosphine-coordinated palladium complexes.
ANOMALOUS ORIENTATION EFFECTS DURING BENZOYLOXYLATIONS BY "SILVER BROMIDE DIBENZOATE"
Bryce-Smith, Derek,Isaacs, Neil S.,Tumi, Seddeg O.
, p. 1471 - 1472 (2007/10/02)
The solid complex formed from bromine and silver benzoate reacts with both arenes and alkenes to form aryl and alkyl benzoates, respectively.Highly unusual substituent effects are observed in the benzoyloxylations of arenes.Electron-withdrawing groups (e.g. -NO2, -CN,-CO-) on the aromatic ring facilitate reaction though directing the attacking reagent exclusively to the meta position.In alkanes, tertiary positions are most prone to attack.
A FACILE METHOD FOR THE OXIDATIVE REMOVAL OF BENZYL ETHERS: THE OXIDATION OF BENZYL ETHERS TO BENZOATES BY RUTHENIUM TETRAOXIDE
Schuda, Paul Francis,Cichowicz, Melissa B.,Heimann, Martha R.
, p. 3829 - 3830 (2007/10/02)
A series of benzyl ethers has been prepared and their oxidation to benzoate esters by ruthenium tetraoxide has been studied.Yields for the oxidation step range from 54 to 96 percent.
