88739-11-1

Basic information

• Product Name: 1,4-Cyclohexadiene, 4-methoxy-2-methyl-1-(1-methylethyl)-
• CAS NO: 88739-11-1
• Molecular Formula: C11H18O
• Molecular Weight: 166.263
• Mol File: 88739-11-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1,4-Cyclohexadiene, 4-methoxy-2-methyl-1-(1-methylethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,4-Cyclohexadiene, 4-methoxy-2-methyl-1-(1-methylethyl)-(88739-11-1)
• EPA Substance Registry System: 1,4-Cyclohexadiene, 4-methoxy-2-methyl-1-(1-methylethyl)-(88739-11-1)

Safety Data

• Hazardous Substances Data: 88739-11-1(Hazardous Substances Data)

Upstream product

• 5436-42-0 2-isopropyl-5-methoxytoluene 

Downstream Products

• 64854-00-8 4-isopropyl-3-methylcyclohex-3-enone 
• 116724-19-7 (S)-(-)-4-isopropyl-3-methyl-2-cyclohexen-1-one 
• 116724-19-7 (R)-4-isopropyl-3-methylcyclohex-2-enone 
• 5436-42-0 2-isopropyl-5-methoxytoluene 

Relevant articles and documents

Total Syntheses of Crinipellins Enabled by Cobalt-Mediated and Palladium-Catalyzed Intramolecular Pauson–Khand Reactions

Efficient total syntheses of the naturally occurring, potent antibiotic compounds (?)-crinipellin A and (?)-crinipellin B are described. The key advanced intermediate, a fully functionalized tetraquinane core, was constructed by a novel thiourea/palladium-catalyzed Pauson–Khand reaction. This intermediate can serve as a common intermediate for the collective total synthesis of other members of the crinipellin family.