88818-16-0Relevant academic research and scientific papers
Rh(III)-Catalyzed C-H amidation with N-Hydroxycarbamates: A new entry to N-Carbamate-protected arylamines
Zhou, Bing,Du, Juanjuan,Yang, Yaxi,Feng, Huijin,Li, Yuanchao
, p. 592 - 595 (2014/04/03)
An unprecedented Rh(III)-catalyzed direct intermolecular C-H amidation with N-hydroxycarbamates has been developed. Different directing groups, such as pyridine, pyrimidine, pyrazole, and N-OMe oxime, can be employed in this C-H amidation process, providi
The electrophilic α-amination of α-alkyl-β-ketoesters with in situ generated nitrosoformates
Selig, Philipp
, p. 7080 - 7082 (2013/07/26)
Lewis acid and oxidation catalysis are merged in the reaction discussed here, which provides access to diversely substituted N-hydroxycarbamates (see scheme). This reaction highlights the potential of nitrosoformates as electrophilic amination reagents as
SYNTHESIS OF RACEMIC DIAMINO-DIDEOXY-LYXOPYRANOSE DERIVATIVES USING ACILNITROSO DIENOPHILES (1).
Defoin, Albert,Schmidlin, Christian,Streith, Jacques
, p. 4515 - 4518 (2007/10/02)
Acylnitroso derivatives, which are obtained by in situ oxidation of the corresponding hydroxamic acids with tetraalkylammonium iodate, react intantaneously in the presence of dihydropyridine 1 leading to the Diels-Alder adducts 4 and 5.These latter ones w
