88841-85-4Relevant academic research and scientific papers
Synthesis of beta-substituted cyclopentenones via carbon alkylation of metalated gamma-methoxycyclopentenyl phenylsulfonyl anion
Kim, Seong Heon,Jin, Zhendong,Fuchs
, p. 4537 - 4538 (2007/10/02)
Metalation of γ-methoxyallyl sulfone 13 provides phenylsulfonyl anion 2a which undergoes alkylation followed by hydrolysis to afford β-substituted cyclopentenones.
A convenient procedure for the preparation of organic selenides
Sakakibara,Katsumata,Watanabe,Toru,Ueno
, p. 377 - 379 (2007/10/02)
Treatment of diphenyl diselenide with tributylphosphine in an alkaline medium forms phenylselenolate ion which converts alkyl halides, α,β-unsaturated ketones, and epoxides into alkyl selenides, (phenylseleno)alkenones, and β-(phenylseleno)alkanols, respe
Reactions of 3-Hydroxyvinyl Selenones with Alkoxides. Oxetane Formation and Fragmentation Reactions
Shimizu, Makoto,Ando, Ryoichi,Kuwajima, Isao
, p. 1230 - 1238 (2007/10/02)
3-Hydroxyvinyl phenyl selenones are prepared and their behavior as conjugate addition acceptors has been investigated.As a result, a selenonyl group has been found to activate the C=C bond for conjugate addition of nucleophiles and further to behave as an
