888481-25-2

Upstream product

• 123748-58-3 (3S)-3,7-dimethyl-oct-6-ene-1,3-diol 
• 69739-34-0 t-butyldimethylsiyl triflate 
• 106-24-1 Geraniol 
• 82188-73-6 (2S,3S)-2,3-epoxygeraniol 
• 888481-16-1 (3S)-3-(tert-butyldimethylsilyloxy)-3,7-dimethyloct-6-enyl benzoate 
• 888481-22-9 (5S)-1,1-dibromo-5-(tert-butyl-dimethyl-silanyloxy)-5-methyl-8-trimethylsilanyl-oct-1-en-7-yne 
• 888481-20-7 (4S)-4-(tert-butyl-dimethyl-silanyloxy)-4,8-dimethyl-1-trimethylsilanyl-non-7-en-1-yne 
• 888481-21-8 (4S)-4-(tert-butyl-dimethyl-silanyloxy)-4-methyl-7-trimethylsilanyl-hept-6-ynal 
• 888481-19-4 (1S)-tert-butyl-[1-(3,3-dibromo-allyl)-1,5-dimethyl-hex-4-enyloxy]-dimethyl-silane 
• 888481-15-0 (3S)-3-hydroxy-3,7-dimethyloct-6-enyl benzoate 
• 888481-17-2 (3S)-3-((tert-butyldimethylsilanyl)oxy)-3,7-dimethyloct-6-en-1-ol 
• 888481-18-3 (3S)-3-(tert-butyl-dimethyl-silanyloxy)-3,7-dimethyl-oct-6-enal 
• 888481-23-0 (4S)-4-(tert-butyl-dimethyl-silanyloxy)-4-methyl-1-trimethylsilanyl-octa-1,7-diyne 
• 212841-98-0 3-methoxy-2-(3-trimethylsilyl-prop-2-ynyl)benzaldehyde 

Downstream Products

• 888481-26-3 (6S)-6-(tert-butyl-dimethyl-silanyloxy)-1-(3-methoxy-2-prop-2-ynyl-phenyl)-6-methyl-nona-2,8-diyn-1-ol 
• 888481-27-4 (6'S)-1-[1,6-bis-(tert-butyl-dimethyl-silanyloxy)-6-methyl-nona-2,8-diynyl]-3-methoxy-2-prop-2-ynyl-benzene 

Relevant academic research and scientific papers

Total synthesis of (-)-8-O-methyltetrangomycin (MM 47755)

A stereoselective total synthesis of the natural antibiotic (-)-8-O-methyltetrangomycin 1 is reported. The essential steps for this convergent synthesis are the transformation of a geraniol epoxide into a chiral octadiyne derivative, which was converted i

The cobalt way to angucyclinones: Asymmetric total synthesis of the antibiotics (+)-rubiginone B2, (-)-tetrangomycin, and ( - ) -8- O-Methyltetrangomycin

A cobalt(I)-mediated convergent and asymmetric total synthesis of angucyclinones with an aromatic B ring has been developed. In the course of our research, we synthesized three naturally occurring anguclinone derivatives, namely, (+)-rubiginone B2/s