888481-15-0

Upstream product

• 106-24-1 Geraniol 
• 82188-73-6 (2S,3S)-2,3-epoxygeraniol 
• 123748-58-3 (3S)-3,7-dimethyl-oct-6-ene-1,3-diol 
• 98-88-4 benzoyl chloride 

Downstream Products

• 888481-16-1 (3S)-3-(tert-butyldimethylsilyloxy)-3,7-dimethyloct-6-enyl benzoate 
• 888481-25-2 (6S)-6-(tert-butyl-dimethyl-silanyloxy)-1-[3-methoxy-2-(3-trimethylsilanyl-prop-2-ynyl)-phenyl]-6-methyl-9-trimethylsilanyl-nona-2,8-diyn-1-ol 
• 888481-27-4 (6'S)-1-[1,6-bis-(tert-butyl-dimethyl-silanyloxy)-6-methyl-nona-2,8-diynyl]-3-methoxy-2-prop-2-ynyl-benzene 
• 888481-26-3 (6S)-6-(tert-butyl-dimethyl-silanyloxy)-1-(3-methoxy-2-prop-2-ynyl-phenyl)-6-methyl-nona-2,8-diyn-1-ol 

Relevant academic research and scientific papers

The cobalt way to angucyclinones: Asymmetric total synthesis of the antibiotics (+)-rubiginone B2, (-)-tetrangomycin, and ( - ) -8- O-Methyltetrangomycin

A cobalt(I)-mediated convergent and asymmetric total synthesis of angucyclinones with an aromatic B ring has been developed. In the course of our research, we synthesized three naturally occurring anguclinone derivatives, namely, (+)-rubiginone B2/s

Total synthesis of (-)-8-O-methyltetrangomycin (MM 47755)

A stereoselective total synthesis of the natural antibiotic (-)-8-O-methyltetrangomycin 1 is reported. The essential steps for this convergent synthesis are the transformation of a geraniol epoxide into a chiral octadiyne derivative, which was converted i