888481-26-3Relevant academic research and scientific papers
The cobalt way to angucyclinones: Asymmetric total synthesis of the antibiotics (+)-rubiginone B2, (-)-tetrangomycin, and ( - ) -8- O-Methyltetrangomycin
Kesenheimer, Christian,Kalogerakis, Aris,Meissner, Anja,Groth, Ulrich
experimental part, p. 8805 - 8821 (2010/10/21)
A cobalt(I)-mediated convergent and asymmetric total synthesis of angucyclinones with an aromatic B ring has been developed. In the course of our research, we synthesized three naturally occurring anguclinone derivatives, namely, (+)-rubiginone B2/s
Total synthesis of (-)-8-O-methyltetrangomycin (MM 47755)
Kesenheimer, Christian,Groth, Ulrich
, p. 2507 - 2510 (2007/10/03)
A stereoselective total synthesis of the natural antibiotic (-)-8-O-methyltetrangomycin 1 is reported. The essential steps for this convergent synthesis are the transformation of a geraniol epoxide into a chiral octadiyne derivative, which was converted i
