888940-16-7

Basic information

• Product Name: RuCl(C₁₄H₂₁C₁₅H₁₀N₃)(N₂C₃₆H₃₈O₈(C₆H₄CN)(C₂H₄SOCH₃))⁽¹⁺⁾*PF₆^(1-)=[RuCl(C₂₉H₃₁N₃)(N₂C₃₆H₃₈O₈(C₆H₄CN)(C₂H₄SOCH₃))]PF₆
• CAS NO: 888940-16-7
• Molecular Weight: 1523.05
• Mol File: 888940-16-7.mol

Chemical Properties

• CAS DataBase Reference: RuCl(C₁₄H₂₁C₁₅H₁₀N₃)(N₂C₃₆H₃₈O₈(C₆H₄CN)(C₂H₄SOCH₃))⁽¹⁺⁾*PF₆^(1-)=[RuCl(C₂₉H₃₁N₃)(N₂C₃₆H₃₈O₈(C₆H₄CN)(C₂H₄SOCH₃))]PF₆(CAS DataBase Reference)
• NIST Chemistry Reference: RuCl(C₁₄H₂₁C₁₅H₁₀N₃)(N₂C₃₆H₃₈O₈(C₆H₄CN)(C₂H₄SOCH₃))⁽¹⁺⁾*PF₆^(1-)=[RuCl(C₂₉H₃₁N₃)(N₂C₃₆H₃₈O₈(C₆H₄CN)(C₂H₄SOCH₃))]PF₆(888940-16-7)
• EPA Substance Registry System: RuCl(C₁₄H₂₁C₁₅H₁₀N₃)(N₂C₃₆H₃₈O₈(C₆H₄CN)(C₂H₄SOCH₃))⁽¹⁺⁾*PF₆^(1-)=[RuCl(C₂₉H₃₁N₃)(N₂C₃₆H₃₈O₈(C₆H₄CN)(C₂H₄SOCH₃))]PF₆(888940-16-7)

Safety Data

• Hazardous Substances Data: 888940-16-7(Hazardous Substances Data)

Upstream product

• 17084-13-8 potassium hexafluorophosphate 
• 660860-77-5 Ru(4'-(3,5-bis(tert-butyl)phenyl)-2,2':6',2''-terpyridine)Cl₃ 
• 888940-08-7 N₂C₁₂H₆(C₆H₄O(CH₂CH₂O)3C₆H₄CN)(C₆H₄O(CH₂CH₂O)3CH₂CH₂SOCH₃) 
• 56-34-8 tetraethylammonium chloride 

Relevant articles and documents

Synthesis and photochemistry of a two-position Ru(terpy)(phen)(L) 2+ scorpionate complex

A dissymmetric 1,10-phenanthroline chelate (N-phen-S) bearing two polyether chains terminated by two monodentate ligands of the benzonitrile (N) and dialkylesulfoxide (S) types was synthesized, characterized, and coordinated to ruthenium. The corresponding Ru(terpy*)(N-phen-S)2+ complexes (terpy* = 4′-(3,5-ditertiobutylphenyl)-2,2′;6′,2″- terpyridine) were fully characterized as being two coordination isomers of the scorpionate type with one of the two tails occupying the sixth position on the coordination sphere. Photoexpulsion of the coordinated tail led to opening of the ruthena-macrocycle and subsequent rearrangement of the bidentate chelate. This rearrangement consisted of a 90° rotation of the phenanthroline around the ruthenium atom. Selective irradiation of one isomer in a mixture of the two was undertaken using band-pass filters; this resulted in an enrichment of the nonirradiated isomer in the mixture. Thermal back-coordination of the tail was investigated in the dark. It took place quantitatively from the corresponding ruthenium chloride complex by trapping of the anion with silver salts.