88919-85-1

Basic information

• Product Name: N'-Methyl-2,3'-bi-indolyl
• Synonyms: N'-Methyl-2,3'-bi-indolyl
• CAS NO: 88919-85-1
• Molecular Formula: C17H14N2
• Molecular Weight: 246.30646
• Mol File: 88919-85-1.mol
• Article Data: 4

Chemical Properties

• Appearance: /
• CAS DataBase Reference: N'-Methyl-2,3'-bi-indolyl(CAS DataBase Reference)
• NIST Chemistry Reference: N'-Methyl-2,3'-bi-indolyl(88919-85-1)
• EPA Substance Registry System: N'-Methyl-2,3'-bi-indolyl(88919-85-1)

Safety Data

• Hazardous Substances Data: 88919-85-1(Hazardous Substances Data)

Upstream product

• 19012-02-3 N-methyl-3-acetylindole 
• 615-43-0 2-iodophenylamine 
• 603-76-9 1-methylindole 
• 1484-27-1 3-bromoindole 

Relevant articles and documents

Modular counter-Fischer?indole synthesis through radical-enolate coupling

A single-electron transfer mediated modular indole formation reaction from a 2-iodoaniline derivative and a ketone has been developed. This transition-metal-free reaction shows a broad substrate scope and unconventional regioselectivity trends. Moreover, important functional groups for further transformation are tolerated under the reaction conditions. Density functional theory studies reveal that the reaction proceeds by metal coordination, which converts a disfavored 5-endo-trig cyclization to an accessible 7-endo-trig process.

SYNTHESIS AND SPECTROSCOPIC CHARACTERISTICS OF 2,3'-BIINDOLYLS AND 2,2'-INDOLYLPYRROLES

A general and selective method has been achieved to synthesize 2,3'-biindolyls and 2,2'-indolylpyrroles through an acid catalyzed reaction of 3-bromoindoles with indoles or pyrroles.I.R., (1)H-NMR, (13)C-NMR and MS data of the dimers are also reported.