88924-86-1

Upstream product

• 95-55-6 2-amino-phenol 
• 1458-98-6 2-methyl-3-bromo-1-propene 
• 614-80-2 2-(acetylamino)phenol 
• 563-47-3 3-Chloro-2-methylpropene 

Downstream Products

• 124476-19-3 N-{2-[3-(4-Bromo-phenylsulfanyl)-2-chloro-2-methyl-propoxy]-phenyl}-acetamide 
• 124476-20-6 N-{2-[2-Chloro-3-(4-chloro-phenylsulfanyl)-2-methyl-propoxy]-phenyl}-acetamide 
• 107195-58-4 2-<2'-(2-Methylallyloxy)anilino>-2-phenylessigsaeure 
• 107195-63-1 2-<2'-(2-Methylallyloxy)-N-nitrosoanilino>-2-phenylessigsaeure 
• 107195-53-9 2-<2'-(2-Methylallyloxy)anilino>-2-phenylessigsaeure-ethylester 
• 107195-68-6 3-<2'-(2-Methylallyloxy)phenyl>-4-phenylsydnon 
• 356558-05-9 N-{2-[(2-methyl-2-oxiranyl)methoxy]phenyl}acetamide 
• 124476-18-2 N-[2-(2-Chloro-2-methyl-3-phenylsulfanyl-propoxy)-phenyl]-acetamide 
• 55000-14-1 2-[(2-methyl-2-propenyl)oxy]benzamine 
• 124476-21-7 N-[2-(2-Chloro-2-methyl-3-p-tolylsulfanyl-propoxy)-phenyl]-acetamide 

Relevant academic research and scientific papers

Chiral N,N Ligands Enabling Palladium-Catalyzed Enantioselective Intramolecular Heck–Matsuda Carbonylation Reactions by Sequential Migratory and CO Insertions

Unprecedented enantioselective intramolecular Heck carbonylation reactions of arenediazonium salts were enabled by a chiral N,N ligand. This reaction constitutes the first enantioselective Heck carbonylation that proceeds through migratory insertion followed by CO insertion. The enantioenriched functionalized dihydrobenzofurans were obtained in good to high yields and enantiomeric ratios of up to 98:2 under mild and operationally simple reaction conditions.

Novel compounds

The invention provides compounds of general formula (I) wherein Q, R, R2, R4, R5, R6, R7 and R8 are as defined in the specification, processes for their preparation, pharmaceutical compositions containing them and their use in therapy.

Intramolecular 1,3-Dipolar Cycloaddition Reactions of Alkenyl-substituted 3,4-Diarylsydnones

The 3,4-diarylsydnones 1 and 12a-e with an allyl or alkenyloxy substituent on the N(3)-phenyl group have been synthesized by classical methods starting from 2-allylaniline and the corresponding alkenyloxyanilines, respectively (Schemes 2 and 3).Whereas th