89002-88-0Relevant articles and documents
Palladium-catalyzed allylic oxidation of 1-(p-toluenesulfonyl)-2-propene and 1-(trimethylsilyl)-1-(p-toluenesulfonyl)-2-propene
Muzart, Jacques,Pete, Jean-Pierre,Riahi, Abdelkhalek
, p. 113 - 120 (2007/10/02)
The course of palladium-catalyzed oxidation of a terminal alkene by t-BuOOH or by O2/H2O is greatly modified when the allylic carbon bears a p-toluenesulfonyl substituent, and allylic oxidation results.Mechanistic explanations of this observation are prop
PALLADIUM CATALIZED OXIDATION OF ALLYLSILANES WITH U.V. LIGHT AND MOLECULAR OXIGEN
Riahi, A.,Cossy, J.,Muzart, J.,Pete, J. P.
, p. 839 - 842 (2007/10/02)
Photolysis of oxygenated acetone solutions of allylsilanes containing small amounts of palladium led to α,β-ethylenic alcohols, aldehydes or ketones.Efficient regiospecific oxidation can be observed when the allylsilane was substituted by an arylsulphonyl group.