89002-90-4Relevant academic research and scientific papers
Preparation of some Allylic Sulphones; Base-catalysed Isomerisation and Deuteriation of Cyclohex-2-enyl p-Tolyl Sulphones
Knight, Derek J.,Lin, Peter,Russell, Simon T.,Whitham, Gordon H.
, p. 2701 - 2706 (2007/10/02)
A summary of the methods used in the preparation of a range of allylic sulphones is given.In the case of the conformationally biased sulphones (5) and (6) stereospecific preparation from the cis- and trans-5-t-butylcyclohex-2-en-1-ols was achieved by rear
Rearrangement of Some Allylic Sulphinate Esters to Allylic Sulphones. Ion-pair and Sigmatropic Shift Mechanisms
Knight, Derek J.,Whitham, Gordon H.,Williams, Jonathan G.
, p. 2149 - 2152 (2007/10/02)
The mechanism of rearrangement of a number of allylic sulphinate esters to the corresponding allylic sulphones on heating in formamide has been investigated as a function of substrate structure.Simple systems such as crotyl and α-methylallyl-sulphinate ap
