89003-00-9Relevant academic research and scientific papers
Rearrangement of Some Allylic Sulphinate Esters to Allylic Sulphones. Ion-pair and Sigmatropic Shift Mechanisms
Knight, Derek J.,Whitham, Gordon H.,Williams, Jonathan G.
, p. 2149 - 2152 (2007/10/02)
The mechanism of rearrangement of a number of allylic sulphinate esters to the corresponding allylic sulphones on heating in formamide has been investigated as a function of substrate structure.Simple systems such as crotyl and α-methylallyl-sulphinate ap
1,3-Rearrangements of Some Allylic Sulphones
Knight, Derek J.,Lin, Peter,Whitham, Gordon H.
, p. 2707 - 2714 (2007/10/02)
The 1,3-rearrangement of a number of acyclic and cyclic allylic p-tolyl sulphones has been found to occur on treatment (a) with benzoyl peroxide (BPO) in CCl4 under reflux or (b) with sodium toluene-p-sulphinate in aqueous acetic acid at 110 deg C.Rearran
1,3-Rearrangements of Allylic Sulphones
Lin, Peter,Whitham, Gordon H.
, p. 1102 - 1103 (2007/10/02)
Three sets of conditions which promote the 1,3-rearrangement of certain allylic sulphones are described.
