89005-38-9Relevant academic research and scientific papers
Alkyl-and arylsulfanyl-substituted unsaturated carbonyl compounds
Kondrashov, Evgeniy V.,Romanov, Alexey R.,Ushakov, Igor A.,Rulev, Alexander Yu.
, p. 18 - 33 (2017/01/17)
A method for the synthesis of captodative sulfanyl enals, enones and enoates via nucleophilic vinylic substitution of corresponding halogen-bearing derivatives has been developed. The one-pot treatment of the haloenoates, haloenones or haloenals with thiols in the presence of organic base leads either to vicinal dithiosubstituted carbonyl-bearing compound or captodative systems with good to excellent yield. The major reaction direction strongly depends on the type of base used.
Chemistry of Allene Sulphoxides: Novel Transformations of Acetylenic Alcohols
Cutting, Ian,Parsons, Philip J.
, p. 1209 - 1210 (2007/10/02)
The preparation and reactions of allenes derived from 1-phenylthio substituted acetylenic alcohols are described; this chemistry offers new routes to allenyl sulphides, acyl anion equivalents, and substituted unsaturated aldehydes.
