89079-89-0Relevant academic research and scientific papers
Synthesis of 2-hydroxytetrahydrofurans by Wacker-type oxidation of 1,1-disubstituted alkenes
Kataoka, Yasutaka,Komori, Saki,Shimizu, Yuhei,Tanaka, Rina,Ura, Yasuyuki
, p. 570 - 574 (2022/02/02)
1,1-Disubstituted alkenes feature high steric hindrance, which renders their Wacker-type oxidation difficult. We demonstrate the stereoselective synthesis of 2-hydroxytetrahydrofurans via the Wacker-type oxidation of 3-methyl-3-buten-1-ols by using a PdCl
EQUIVALENTS ANOINIQUES HOMOENOLATES ISSUS D'ENEPHOSPHORAMIDES: REACTION AVEC LA BENZOPHENONE
Coutrot, Ph.,Dormoy, J. R.,Moukimou, A.
, p. C25 - C28 (2007/10/02)
α-Phosphoramidolithium substituted allylic carbanions are used as homoenolate reagents with benzophenone and give regioselectively α- or γ-hydroxyalkylation products.Replacement of lithium by magnesium leads to γ substitution almost exclusively.Acidic hyd
