89108-49-6

Basic information

• Product Name: Benzene, 1-(1-azidoethenyl)-4-methyl-
• CAS NO: 89108-49-6
• Molecular Formula: C9H9N3
• Molecular Weight: 159.191
• Mol File: 89108-49-6.mol
• Article Data: 40

Chemical Properties

• CAS DataBase Reference: Benzene, 1-(1-azidoethenyl)-4-methyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-(1-azidoethenyl)-4-methyl-(89108-49-6)
• EPA Substance Registry System: Benzene, 1-(1-azidoethenyl)-4-methyl-(89108-49-6)

Safety Data

• Hazardous Substances Data: 89108-49-6(Hazardous Substances Data)

Upstream product

• 1352574-56-1 1-(1-azido-2-bromoethyl)-4-methylbenzene 
• 33458-08-1 1-(1,2-dibromoethyl)-4-methylbenzene 
• 766-97-2 4-n-methylphenylacetylene 
• 1092459-96-5 1-(1-azido-2-iodoethyl)-4-methylbenzene 
• 622-97-9 1-ethenyl-4-methylbenzene 

Downstream Products

• 1073483-63-2 ethyl 2-methyl-5-p-tolyl-1H-pyrrole-3-carboxylate 
• 1073483-85-8 1-(2-methyl-5-p-tolyl-1H-pyrrol-3-yl)ethanone 
• 65964-60-5 2-para-tolylimidazo[1,2-a]pyridine 
• 65964-61-6 7-methyl-2-(4-methylphenyl)imidazo[1,2-a]pyridine 
• 61001-04-5 2-(4-methylphenyl)imidazo[2,1-a]isoquinoline 
• 2001-28-7 2-phenyl-1-p-tolyl-ethanone 
• 73475-24-8 2-(p-methylphenyl)aziridine 

Relevant articles and documents

Photoredox-catalyzed synthesis of N-unsubstituted enaminosulfones from vinyl azides and sulfinates

A metal-free visible light photoredox-catalyzed synthesis of N-unsubstituted enaminosulfones from vinyl azides and sodium sulfinates in moderate to high yields is described. The reaction proceeds in ethanol and uses eosin Y as a readily available photocatalyst in combination with nitrobenzene as an electron shuttle. Taking into account the number of steps involved (generation of the sulfonyl radical, its addition to the double bond, elimination of molecular nitrogen with formation of an iminyl radical, followed by its reduction and protonation) as well as the number of redox-active reaction partners involved, the selectivity of the process is quite impressive.

A sustainable strategy for the straightforward preparation of 2H-azirines and highly functionalized NH-aziridines from vinyl azides using a single solvent flow-batch approach

The reported flow-batch approach enables the easy preparation of 2H-azirines and their stereoselective transformation into highly functionalized NH-aziridines, starting from vinyl azides and organolithium compounds. The protocol has been developed using c

Electrochemically Induced Synthesis of Sulfonylated N-Unsubstituted Enamines from Vinyl Azides and Sulfonyl Hydrazides

Sulfonylated N-unsubstituted enamines were synthesized through a chain of chemical and electrochemical transformations via sulfonylation of vinyl azides. The disclosing of the N-unsubstituted enamines synthesis was based on a unique property of the azido group, which is its ability to eliminate the N2 molecule. Furthermore, a formal paradox is observed: A double bond reacts and a double bond is retained. Electrosynthesis proceeded in an undivided cell equipped with a graphite anode and a stainless steel cathode; NH4I was used as a supporting electrolyte.