89154-38-1Relevant academic research and scientific papers
ISOMERIZATION OF α-ACETYLENIC KETONES
Shvartsberg, M. S.,Fedenok, L. G.
, p. 1906 - 1910 (2007/10/02)
A method is suggested for isomerization of α-acetylenic ketones with migration of oxo group from position 1 to position 3 and of the triple bond position 2 to position 1 of the ketoacetylenic fragment; it consists of addition of Et2NH at the triple bond o
SYNTHESIS OF ACETYLENIC KETONES
Zanina, A. S.,Shergina, I. S.,Sokolov, I. E.,Kotlyarevskii, I. L.
, p. 2307 - 2311 (2007/10/02)
A general preparative method of synthesis of acetylenic ketones was developed based on acylation of terminal acetylenes with acid chlorides in the presence of Cu(I) chloride.
