89264-12-0Relevant academic research and scientific papers
A Concise Synthesis of Functionalised gem-Difluoroalkenes via the Addition of Organolithium Reagents to α-Trifluoromethylstyrene
Begue, Jean-Pierre,Bonnet-Delpon, Daniele,Rock, Michael H.
, p. 5003 - 5006 (1995)
The treatment of α-trifluoromethyl styrene with organolithium reagents results in the selective formation of gem-difluoroalkenes in good to excellent yield.This reaction has been applied to the synthesis of a range functionalised gem-difluoroalkenes. - Ke
ORGANOCUPRATE-INDUCED SUBSTITUTION OF THE ENOL OXYGEN MOIETY IN 2,2-DIFLUORO ENOL PHOSPHATES WITH ALLYL HALIDES: A NOVEL ROUTE TO gem-DIFLUOROOLEFINS FROM CHLORODIFLUOROMETHYL KETONES
Ishihara, Takashi,Yamana, Masayuki,Ando, Teiichi
, p. 5657 - 5660 (2007/10/02)
2,2-Difluoro-1-arylethenyl diphenyl phosphates, prepared from chlorodifluoromethyl ketones and diphenyl phosphite, reacted with dibutylcopperlithium and successively with various allyl halides to give allylated gem-difluoroolefins in moderate to excellent
