89358-10-1

Basic information

• Product Name: 5-Hexene-1,3-diol, 3-methyl-1-phenyl-
• CAS NO: 89358-10-1
• Molecular Formula: C13H18O2
• Molecular Weight: 206.285
• Mol File: 89358-10-1.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 5-Hexene-1,3-diol, 3-methyl-1-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 5-Hexene-1,3-diol, 3-methyl-1-phenyl-(89358-10-1)
• EPA Substance Registry System: 5-Hexene-1,3-diol, 3-methyl-1-phenyl-(89358-10-1)

Safety Data

• Hazardous Substances Data: 89358-10-1(Hazardous Substances Data)

Upstream product

• 20924-77-0 1-chloro-2-methylpent-4-en-2-ol 
• 100-52-7 benzaldehyde 
• 209806-34-8 3-Allyl-3-methyl-oxirane-2-carboxylic acid methoxy-methyl-amide 
• 13891-87-7 pent-4-en-2-one 
• 5381-93-1 1-hydroxy-1-phenyl-3-butanone 
• 6336-44-3 allylboronic acid 

Relevant articles and documents

Tandem aldol-allylation and aldol-aldol reactions with ketone-derived enolsilanes: Highly diastereoselective single-step synthesis of complex tertiary carbinols

A new tandem aldol-allylation reaction employing ketone-derived enolates has been developed that leads to the rapid, diastereoselective synthesis of tertiary carbinol containing fragments with relevance to polyketide natural product synthesis. In addition

Indirect Tertiary Alcohol Enantiocontrol by Acylative Organocatalytic Kinetic Resolution

The stereocontrol of tertiary alcohols represents a recurrent challenge in organic synthesis. In the present paper, we describe a simple, efficient, and indirect method to enantioselectively prepare tertiary alcohols through a chiral isothiourea catalyzed

β-Substituted Organolithium Compounds from Chlorohydrins: Application to the Direct Synthesis of Bifunctionalized Organic Cpmpounds

The reaction of different chlorohydrins with n-butyl-lithium at -78 deg C followed by metallation wiht lithium naphthalenide at the same temperature leads to very reactive organolithium compounds bearing an alkoxide function at the β-position with respect to metal.The reaction of these intermediates with several electriphiles leads to mono- as well as bi-functionalized organic compounds.Thus, treatment of these dianions with deuterium oxide, oxygen, carbon dioxide, benzyl bromide, dimethyl disulphide, and carbonyl compounds, gave 2-deuterioalcohols, 1,2-diols, β-hydroxy-acids, 2-benzyl alcohols, 2-hydroxy-thioethers, and 1,3-diols respectively.The preparation of β-substituted organolithium derivatives can be alternatively carried out starting from α-chloroketones by the same procedure.When the lithium atom is linked to a secondary carbon atom the dianions are very unstable and decompose, even at -100 deg C, by β-elimination yielding the corresponding olefins.