894777-14-1 Usage
Description
1'-(Aminocarbonyl)-1,2,3,4,5-pentaphenyl-ferrocene is an organic compound that features a ferrocene core with five phenyl groups attached to it. The molecule also contains an aminocarbonyl group at the 1' position, which contributes to its unique chemical properties and potential applications in various fields.
Uses
Used in Organic Synthesis:
1'-(Aminocarbonyl)-1,2,3,4,5-pentaphenyl-ferrocene is used as a reactant for asymmetric Aza-Claisen rearrangement, a reaction that is important for the synthesis of complex organic molecules with specific stereochemistry.
Used in Palladium Chemistry:
1'-(Aminocarbonyl)-1,2,3,4,5-pentaphenyl-ferrocene is used as a reactant for the synthesis and diastereoselective ortholithiation/cyclopalladation. This process is crucial for the preparation of palladium complexes with specific stereochemistry, which are valuable in various catalytic applications.
Used in Catalyst Synthesis:
1'-(Aminocarbonyl)-1,2,3,4,5-pentaphenyl-ferrocene is used as a reactant for the synthesis of enantioselective ferrocenyl-imidazoline palladacycle catalysts. These catalysts are essential in asymmetric catalysis, where they can selectively promote reactions to produce enantiomerically pure products, which are important in pharmaceuticals and other industries.
Check Digit Verification of cas no
The CAS Registry Mumber 894777-14-1 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 8,9,4,7,7 and 7 respectively; the second part has 2 digits, 1 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 894777-14:
(8*8)+(7*9)+(6*4)+(5*7)+(4*7)+(3*7)+(2*1)+(1*4)=241
241 % 10 = 1
So 894777-14-1 is a valid CAS Registry Number.
894777-14-1Relevant articles and documents
Synthesis and diastereoselective ortho-lithiation/cyclopalladation of enantiopure [2-Imidazolyl]-1′,2′,3′,4′,5′- pentamethylferrocenes and -1′,2′,3′,4′,5′- pentaphenylferrocenes
Peters, Rene,Xin, Zhuo-Qun,Fischer, Daniel F.,Schweizer, W. Bernd
, p. 2917 - 2920 (2006)
Convenient synthetic routes to enantiomerically pure 1′,2′, 3′,4′,5′-pentamethyl and -pentaphenylferrocenyl imidazolines are described. While the former complexes were diastereoselectively ortho-lithiated and subsequently functionalized by trapping with v
