895166-57-1Relevant academic research and scientific papers
A simple synthetic route to the formation of tetracopper(1) 2-mercaptothiazoline compounds - The crystal structures of [Cu 4(S-thiaz)4(PEt2Ph)2], [Cu 4(S-thiaz)4(PEt3)2], [Cu 4(S-thiaz)4]2, and [Cu4(S-thiaz) 4]4
Fuhr, Olaf,Fernandez-Recio, Lucia,Fenske, Dieter
, p. 251 - 256 (2006)
Reactions of copper(I) acetate with 2-mercaptothiazoline (HS-thiaz) in the presence of tertiary phosphines lead to the formation of tetranuclear sulphur-bridged copper complexes. Depending on the reaction conditions, isolated clusters ([Cu4(S-thiaz)4(PR3)2] (PR3 = PPh3 (1), PEt2Ph (2), PEt3 (3)), oligomeric compounds ([Cu4(S-thiaz)4] (4) and [Cu4(S-thiaz)4]4 (5)), or a one-dimensional polymer ([Cu4(S-thiaz)4]∞ (6)) are formed. The structures of the compounds 2-5 have been determined by single crystal X-ray analysis.
