89556-80-9Relevant academic research and scientific papers
Chemistry of Oxaziridines. 8. Asymmetric Oxidation of Nonfunctionalized Sulfides to Sulfoxides with High Enantioselectivity by 2-Sulfamyloxaziridines. The Influence of the Oxaziridine C-Aryl Group on the Asymmetric Induction
Davis, Franklin A.,McCauley, John P.,Chattopadhyay, Sankar,Harakal, Mark E.,Towson, James C.,et al.
, p. 3370 - 3377 (2007/10/02)
Chiral sulfamyloxaziridines 6 and 7, prepared by biphasic oxidation of the corresponding sulfamylimines 5, afford high asymmetric induction for the oxidation of a series of nonfunctionalized sulfides to sulfoxides (53-91percent ee).The enantioselectivitie
Chiral Sulfamides: Synthesis of Optically Active 2-Sulfamyloxaziridines. High Enantioselectivity in the Asymmetric Oxidation of Sulfides to Sulfoxides
Davis, Franklin A.,McCauley, John P.,Harakal, Mark E.
, p. 1465 - 1467 (2007/10/02)
The first synthesis of optically active 2-sulfamyloxaziridines 4a-d and 5a-d, which affords high enantioselectivity (38-68 percent ee) for asymmetric oxidations of sulfides to sulfoxides, is described.
