89577-17-3Relevant academic research and scientific papers
The Halogenation of Toluene with Sulphuryl Chloride and Dichlorine in the Presence of Transition Metal Complexes
Davis, Reg,Durrant, Jim L. A.,Rowland, Cristopher C.
, p. 119 - 134 (1986)
A detailed study has been made of the halogenation of toluene in the presence of a range of transition metal complexes.Both side-chain and ring chlorination are observed, the favoured route depending on the metal complex.Side-chain halogenation, in the presence of and (M= Pd, Pt), has been shown to proceed by a free radical chain reaction in which the metal complex acts solely as an initiator.In the presence of, (M= Mn, Re), , and , ring chlorinated products are formed by a Friedel-Crafts mechanism.
Synthesis, characterization and reactivity of dinuclear rhenium complexes containing hemilabile phosphines as ligands: X-ray structures of diax-[Re2(CO)8{κ1(P)-Ph2P(CH2)2CN}2], [
Pe?a, Deisy,Otero, Yomaira,Arce, Alejandro,García, Juan M.,Coll, David S.,Ocando-Mavarez, Edgar,Machado, Rubén,González, Teresa
, p. 178 - 185 (2015/11/16)
The reaction of [Re2(CO)8(MeCN)2] with cyanoethylphosphines affords mono- and disubstituted compounds where the phosphine ligand is κ1(P)-coordinated. When diallylphosphines are used as ligands, the μ:κ3/s
THE USE OF SO2Cl2 IN ORGANOMETALLIC CHEMISTRY. CONVENIENT HIGH YIELD SYNTHESES OF AND (M = Mn or Re)
Manning, A. R.,McNally, Gerald,Davis, Reg,Rowland, Christopher C.
, p. C15 - C16 (2007/10/02)
Depending on the substrate and the reaction conditions, SO2Cl2 is a useful reagent which brings about either chlorination or the formation of cationic species on reaction with transition metal carbonyl complexes.
Associative Substitution Reactions of *Re(CO)5
Fox, Arnold,Malito, John,Poe, Anthony
, p. 1052 - 1053 (2007/10/02)
Studies of competition between substitution and chlorine abstraction reactions of photochemically generated *Re(CO)5 radicals show that substitution proceeds via a second-order associative path and not via CO dissociation.
