89583-55-1Relevant academic research and scientific papers
HALOGENATED ETHERS. XVIII. KINETICS OF THE COMBINED CHLORINATION OF 3-CHLOROPROPENE WITH R-SUBSTITUTED ALCOHOLS
Larionova, L. A.,V'yunov, K. A.,Ginak, A. I.
, p. 243 - 247 (2007/10/02)
The effect of temperature on the kinetics of the combined chlorination of 3-chloropropene with R-substituted alcohols was investigated.It was found that isokinetic relationships exist in the investigated reaction series; the reason for the appearance of a compensation relationships are discussed.
Three Component Reactions. XII. Alkoxychlorination of 3-Chloropropene and 3-Methoxypropene
Beger, J.,Schiefer, H.
, p. 1039 - 1047 (2007/10/02)
By capillar GLC and 13C-n.m.r. spectroscopy was demonstrated, that - in contrast to the communications of other authors - both expected isomeric alkoxychlorination products are formed in the chlorination of 3-chloropropene in presence of several alkanols.Isomers with anti-Markovnikov orientation dominated in all pairs of isomers which we have identified.Analogous product relations were found in the chlorination as well as in the methoxychlorination of 3-methoxypropene.
