896718-37-9

Upstream product

• 13329-40-3 4-Iodoacetophenone 
• 593-56-6 N-methoxylamine hydrochloride 

Downstream Products

• 1268256-02-5 N-[1-(4-iodo-phenyl)-ethyl]-O-methyl-hydroxylamine 
• 1268252-73-8 3-difluoromethyl-1-methyl-1H-pyrazole-4-carboxylic acid [1-(4-iodo-phenyl)-ethyl]-methoxy-amide 
• 1268252-80-7 3-difluoromethyl-1-methyl-1H-pyrazole-4-carboxylic acid {1-[4-(4-chloro-phenoxy)-phenyl]-ethyl}-methoxy-amide 
• 249291-84-7 1-(2-fluoro-4-iodophenyl)ethan-1-one 
• 1447826-92-7 5-iodo-2-(1-(methoxyimino)ethyl)benzonitrile 

Relevant academic research and scientific papers

Rhodium(III)-Catalyzed Oxidative Annulation of Ketoximes with Sulfonamide: A Direct Approach to Indazoles

A rhodium(III)-catalyzed intermolecular C-H amination of ketoxime and iodobenzene diacetate-enabled N-N bond formation in the synthesis of indazoles has been developed. A variety of functional groups were well tolerated, providing the corresponding products in moderate to good yields. Moreover, the nitro-substituted ketoximes are well compatible in this reaction, leading to the corresponding products in moderate to good yields.

Palladium-Catalyzed C(sp2)-H Acetoxylation via Electrochemical Oxidation

Palladium-catalyzed arene C(sp2)-H acetoxylation has emerged as a powerful tool to construct a carbon-oxygen (C-O) bond. However, the requirement of stoichiometric chemical oxidants for this transformation possesses a significant disadvantage.

Synthesis of 2-fluorocholine aryl carbonyl compounds

The invention provides a method for synthesizing 2-fluoroarylcarbonyl compounds, which comprises the following steps: converting arylcarbonyl compounds into corresponding carbonyl oxime ether compounds, mildly implementing aryl hydrocarbon chain direct fluoridation of high-selectivity oximido substituent group ortho-position in the presence of a palladium catalyst, a fluoridation reagent and additives, and finally, rehydrolyzing oxime ethers under the action of acid to obtain the 2-fluoroarylcarbonyl compounds. The fluoridation method has the advantages of mild reaction conditions, high substrate adaptability, high fluoridation selectivity and the like, is simple to operate, and has higher application research value.

Rhodium-catalyzed directed C-H cyanation of arenes with N-cyano-N-phenyl-p-toluenesulfonamide

A Rh-catalyzed directed C-H cyanation reaction was developed for the first time as a practical method for the synthesis of aromatic nitriles. N-Cyano-N-phenyl-p-toluenesulfonamide, a user-friendly cyanation reagent, was used in the transformation. Many different directing groups can be used in this C-H cyanation process, and the reaction tolerates a variety of synthetically important functional groups.

N-ALKOXYCARBOXAMIDES AND THEIR USE AS MICROBIOCIDES

Compounds of formula (I) in which the substituents are as defined in claim 1, are suitable for use as microbiocides.