89736-77-6Relevant articles and documents
ESTER COMPOUND, GELLING AGENT, AND COMPOSITION
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Paragraph 0058, (2021/03/05)
PROBLEM TO BE SOLVED: To provide a novel low molecular weight compound, a gelling agent and a composition that are excellent in gell recoverability and capability of gelling to an oil gel. SOLUTION: An ester compound is represented by one of the general formulas (1), (2) and (3). (In the general formulas (1), (2) and (3), R1 and R4 are each an alkyl group or the like; and R2 and R3 are each an alkylene group or the like.) SELECTED DRAWING: Figure 1 COPYRIGHT: (C)2021,JPO&INPIT
One-Pot Transformation of Aliphatic Carboxylic Acids into N-Alkylsuccin-imides with NIS and NCS/NaI
Nakai, Yuhta,Moriyama, Katsuhiko,Togo, Hideo
, p. 768 - 772 (2017/01/18)
Primary aliphatic carboxylic acids were treated with N-iodosuccinimide (NIS) in 1,2-dichloroethane to form the corresponding alkyl iodides under warming conditions. Based on these results, those aliphatic carboxylic acids were treated with NIS, followed by the reaction with K2CO3to give the corresponding N-alkylsuccinimides in good yields in one pot. Moreover, those aliphatic carboxylic acids were treated with N-chlorosuccinimide (NCS) and NaI, followed by the reaction with K2CO3to provide the corresponding N-alkylsuccinimides in good to moderate yields in one pot. By using the present method, successive treatment of primary aliphatic carboxylic acids (10 mmol) with NIS, K2CO3, and then hydrazine provided the corresponding decarboxylated primary amines in good yield.
Versatile and sustainable synthesis of cyclic imides from dicarboxylic acids and amines by Nb2O5 as a base-tolerant heterogeneous lewis acid catalyst
Ali, Md. Ayub,Siddiki, S. M. A. Hakim,Kon, Kenichi,Hasegawa, Junya,Shimizu, Kenichi
supporting information, p. 14256 - 14260 (2015/01/09)
Catalytic condensation of dicarboxylics acid and amines without excess amount of activating reagents is the most atom-efficient but unprecedented synthetic method of cyclic imides. Here we present the first general catalytic method, proceeding selectively and efficiently in the presence of a commercial Nb2O5 as a reusable and base-tolerant heterogeneous Lewis acid catalyst. The method is effective for the direct synthesis of pharmaceutically or industrially important cyclic imides, such as phensuximide, N-hydroxyphthalimide (NHPI), and unsubstituted cyclic imides from dicarboxylic acid or anhydrides with amines, hydroxylamine, or ammonia.