89738-82-9

Upstream product

• 677-22-5 tert-butylmagnesium chloride 
• 84543-57-7 2,4,6-tri-(tert-butyl)thiobenzaldehyde 
• 594-19-4 tert.-butyl lithium 
• 3975-77-7 1-bromo-2,4,6-tri-tert-butylbenzene 
• 92635-34-2 t-butyl-2,2-dimethyl-1-(1,3,5-tri-t-butylbicyclo<2.2.0>hexa-2,5-dien-2-yl)propyl sulfide 

Relevant academic research and scientific papers

THERMAL AND PHOTOCHEMICAL REACTIONS OF A STABLE THIOBENZALDEHYDE, 2,4,6-TRI-t-BUTYLTHIOBENZALDEHYDE

Thermal and photochemical reactions of the title compound gave benzothiolane 2 in high yield; the reaction with free radicals also afforded 2 along with some other products.

Synthesis, Structure, and Some Reactions of (2,4,6-Tri-t-butyl)thiobenzaldehyde, the First Stable Aromatic Thioaldehyde

The title compound 1 was synthesized by the reaction of 2,4,6-tri-t-butylphenyllithium with O-ethyl thioformate or that of 2,4,6-tri-t-butylbenzaldehyde hydrazone with disulfur dichloride in the presence of triethylamine. The thioaldehyde 1 is a purple cr

NEW ASPECTS OF ORGANOSELENIUM COMPOUNDS CONTAINING GROUP 14 ELEMENTS

The synthesis and reactivities of double bond compounds between Group 14 and Group 16 elements have been reported.Specifically the chemistry of M=X type compounds (C=Se, Ge=S, Sn=S, Sn=Se) are described.

Unusually Ready Cleavage of an S-Cα Bond in Sterically Crowded Sulphoxides

Oxidation of sterically crowded sulphides containing a 2,4,6-tri-t-butylphenyl group or its Dewar benzene analogue affords unusually unstable sulphoxides which undergo ready heterolytic S-Cα cleavage to give indan derivatives and sulphenic acid

REACTIONS OF A STABLE THIOBENZALDEHYDE WITH ORGANOMETALLICS

Rections of 2,4,6-tri-t-butylthiobenzaldehyde with Grignard and organolithium reagents gave products via the anion radical of the thioaldehyde.The first example of dimerization of thioketyl radicals was also presented.