898267-70-4

Basic information

• Product Name: trans-3-bromo-1-benzylsulfonyl-1-propene
• CAS NO: 898267-70-4
• Molecular Weight: 275.166
• Mol File: 898267-70-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: trans-3-bromo-1-benzylsulfonyl-1-propene(CAS DataBase Reference)
• NIST Chemistry Reference: trans-3-bromo-1-benzylsulfonyl-1-propene(898267-70-4)
• EPA Substance Registry System: trans-3-bromo-1-benzylsulfonyl-1-propene(898267-70-4)

Safety Data

• Hazardous Substances Data: 898267-70-4(Hazardous Substances Data)

Upstream product

• 110-86-1 pyridine 
• 873383-81-4 benzyl-(2,3-dibromo-propyl)-sulfone 
• 71-43-2 benzene 
• 100-53-8 phenylmethanethiol 
• 6937-97-9 allyl(benzyl)sulfide 
• 6633-92-7 ((allylsulfonyl)methyl)benzene 
• 889862-39-9 trans-3-benzylsulfonyl-2-propen-1-ol 

Downstream Products

• 6633-92-7 ((allylsulfonyl)methyl)benzene 
• 92904-86-4 1-ethanesulfonyl-3-phenylmethanesulfonyl-propane 
• 889862-39-9 trans-3-benzylsulfonyl-2-propen-1-ol 
• 898267-76-0 trans-3-benzylsulfonyl-2-propene acetate 
• 95494-81-8 1-ethanesulfonyl-3-phenylmethanesulfonyl-propene 
• 95494-80-7 3-ethanesulfonyl-1-phenylmethanesulfonyl-propene 

Relevant articles and documents

The epoxy-Ramberg-Baecklund reaction (ERBR): A sulfone-based method for the synthesis of allylic alcohols

The epoxy-Ramberg-Baecklund reaction (ERBR) is outlined, in which α,β-epoxy sulfones are converted into a range of mono-, di- and tri-substituted allylic alcohols, on treatment with base. Modification of this method enabled the preparation of enantio-enriched allylic alcohols following the diastereoselective epoxidation of enantio-enriched vinyl sulfones that were accessed efficiently from the chiral pool. The scope, optimisation and limitations of the ERBR as a method for the preparation of allylic alcohols are discussed. Wiley-VCH Verlag GmbH & Co. KGaA, 2006.