6937-97-9

Basic information

• Product Name: [(prop-2-en-1-ylsulfanyl)methyl]benzene
• Synonyms: [(Allylsulfanyl)methyl]benzene; 3-(Benzylthio)propene; Allyl(benzyl)sulfide
• CAS NO: 6937-97-9
• Molecular Formula: C₁₀H₁₂S
• Molecular Weight: 164.2673
• Mol File: 6937-97-9.mol
• Article Data: 47

Chemical Properties

• Boiling Point: 239.4°C at 760 mmHg
• Flash Point: 91.3°C
• Density: 0.999g/cm³
• Vapor Pressure: 0.0621mmHg at 25°C
• Refractive Index: 1.555
• CAS DataBase Reference: [(prop-2-en-1-ylsulfanyl)methyl]benzene(CAS DataBase Reference)
• NIST Chemistry Reference: [(prop-2-en-1-ylsulfanyl)methyl]benzene(6937-97-9)
• EPA Substance Registry System: [(prop-2-en-1-ylsulfanyl)methyl]benzene(6937-97-9)

Safety Data

• Hazardous Substances Data: 6937-97-9(Hazardous Substances Data)

Usage

General Description

"[(prop-2-en-1-ylsulfanyl)methyl]benzene" is a chemical compound with the molecular formula C10H12S. It is a derivative of benzene with a propenylsulfanyl methyl group attached to the benzene ring. The compound is commonly used in the synthesis of organic compounds and can also be used as a starting material for the production of other chemicals. It has a wide range of industrial applications, including as a precursor for the synthesis of pharmaceuticals, pesticides, and other organic compounds. The compound is flammable and may pose health hazards if not handled properly, so it should be handled with care and in a well-ventilated area.

Upstream product

• 106-95-6 allyl bromide 
• 100-53-8 phenylmethanethiol 
• 3492-64-6 sodium benzylmercaptide 
• 107-05-1 3-chloroprop-1-ene 
• 150-60-7 dibenzyl disulphide 
• 6728-21-8 allyl mesylate 
• 24850-33-7 allyltributylstanane 
• 102391-59-3 Allyl-benzyl-dithiocarbonate 
• 69614-87-5 N-methyl-N-<<(phenylmethyl)thio>methylene>methanaminium chloride 
• 156275-86-4 Benzylsulfanyl-triisopropyl-silane 
• 100-51-6 benzyl alcohol 
• 120017-05-2 Thiocarbonic acid O-allyl ester S-benzyl ester 
• 870-23-5 prop-2-ene-1-thiol 
• 100-39-0 benzyl bromide 

Downstream Products

• 140927-78-2 3-chloro-2-methoxypropyl benzyl sulfide 
• 140927-79-3 3-chloro-2-ethoxypropyl benzyl sulfide 
• 821-11-4 1,4-butenediol 
• 1043521-76-1 4-(benzylthio)-2-buten-1-ol 
• 1043521-79-4 1,4-bis(benzylthio)-2-butene 
• 1609958-95-3 2-(benzylthio)-N,2-diphenyl-N-tosylpent-4-enamide 
• 63297-72-3 1-phenyl-1-(methylthio)-3-butene 
• 75238-64-1 1-Methyl-2-(1-methylsulfanyl-allyl)-benzene 
• 75238-66-3 trans (methylthio)-1-p-tolyl-3 propene 
• 75238-67-4 methyl(4-phenylbut-1-en-1-yl)sulfane 
• 75238-63-0 Benzyl-1-butinyl-sulfid 
• 75238-68-5 methyl(4-phenylbut-1-en-1-yl)sulfane 
• 75238-62-9 benzyl but-3-en-2-yl sulfide 
• 78286-83-6 2-(Methyl-phenyl-amino)-propane-1-thiol 

Relevant articles and documents

Sulfur ylides generated from the reaction of adamantylidene and phenylcarbene with sulfur substrates

Reaction of adamantylidene and phenylcarbene with ethylthiol, ethylene dithiol, allylethylsulfide, allylphenylsulfide, and trimethylenesulfide involves the formation of a sulfur ylide intermediate, followed by H-migration, 2,3-sigmatropic shift, or ring opening to give sulfides. The sulfur ylide formed in the reaction of phenylcarbene with trimethylenesulfide is directly observed by laser flash photolytic techniques.

A mild and chemoselective CALB biocatalysed synthesis of sulfoxides exploiting the dual role of AcOEt as solvent and reagent

A mild, chemoselective and sustainable biocatalysed synthesis of sulfoxides has been developed exploiting CALB and using AcOEt with a dual role of more environmentally friendly reaction solvent and enzyme substrate. A series of sulfoxides, including the drug omeprazole, have been synthesised in high yields and with excellent E-factors.

Ruthenium-catalyzed decarboxylative C-S cross-coupling of carbonothioate: synthesis of allyl(aryl)sulfide

A novel ruthenium-catalyzed decarboxylative cross-coupling of carbonothioate is disclosed. This method provides straightforward access to the corresponding allyl(aryl)sulfide derivatives in generally good to excellent yields under mild conditions and feat