6633-92-7

Basic information

• Product Name: [(prop-2-en-1-ylsulfonyl)methyl]benzene
• CAS NO: 6633-92-7
• Molecular Formula: C₁₀H₁₂O₂S
• Molecular Weight: 196.2661
• Mol File: 6633-92-7.mol
• Article Data: 8

Chemical Properties

• Boiling Point: 367.1°C at 760 mmHg
• Flash Point: 219.3°C
• Density: 1.145g/cm³
• Vapor Pressure: 2.96E-05mmHg at 25°C
• Refractive Index: 1.541
• CAS DataBase Reference: [(prop-2-en-1-ylsulfonyl)methyl]benzene(CAS DataBase Reference)
• NIST Chemistry Reference: [(prop-2-en-1-ylsulfonyl)methyl]benzene(6633-92-7)
• EPA Substance Registry System: [(prop-2-en-1-ylsulfonyl)methyl]benzene(6633-92-7)

Safety Data

• Hazardous Substances Data: 6633-92-7(Hazardous Substances Data)

Usage

General Description

[(prop-2-en-1-ylsulfonyl)methyl]benzene is a chemical compound with the molecular formula C10H12O2S. It is also known as styrenesulfonylmethylbenzene and is a benzene derivative with a sulfonylmethyl group attached to a styrene moiety. [(prop-2-en-1-ylsulfonyl)methyl]benzene is commonly used in the synthesis of pharmaceuticals and agrochemicals. It is also used as a building block in the production of polymers and resins.[(prop-2-en-1-ylsulfonyl)methyl]benzene is a clear, colorless liquid with a strong odor and is considered to be a hazardous material that requires proper handling and storage. Overall, this chemical compound has various industrial and commercial applications but should be used with caution due to its potential hazards.

Upstream product

• 898267-70-4 trans-3-bromo-1-benzylsulfonyl-1-propene 
• 64-19-7 acetic acid 
• 6937-97-9 allyl(benzyl)sulfide 
• 100-53-8 phenylmethanethiol 
• 100-39-0 benzyl bromide 
• 1730-25-2 allylmagnesium bromide 
• 187737-37-7 propene 
• 889862-39-9 trans-3-benzylsulfonyl-2-propen-1-ol 
• 3492-64-6 sodium benzylmercaptide 
• 107-05-1 3-chloroprop-1-ene 
• 106-95-6 allyl bromide 
• 90875-94-8 benzyl 3-chloropropyl sulfone 
• 13284-96-3 2-propenyl benzyl sulfoxide 

Downstream Products

• 889862-39-9 trans-3-benzylsulfonyl-2-propen-1-ol 
• 6178-56-9 1-(phenylmethylsulfonyl)propan-2-ol 
• 91061-28-8 benzyl 2-propenyl sulfone 
• 860747-30-4 phenylmethanesulfonyl-acetaldehyde 
• 736946-10-4 benzyl-(2,3-dichloro-propyl)-sulfone 
• 873383-81-4 benzyl-(2,3-dibromo-propyl)-sulfone 
• 154619-07-5 3-phenylmethanesulfonyl-propan-1-ol 
• 112654-22-5 2-Allyl-2-(1,2-diphenyl-ethyl)-malononitrile 
• 898267-70-4 trans-3-bromo-1-benzylsulfonyl-1-propene 
• 856060-62-3 benzyl-(2-iodo-propyl)-sulfone 
• 5877-15-6 benzyl-(2-chloro-propyl)-sulfone 
• 95494-80-7 3-ethanesulfonyl-1-phenylmethanesulfonyl-propene 
• 92904-86-4 1-ethanesulfonyl-3-phenylmethanesulfonyl-propane 

Relevant articles and documents

A mild and chemoselective CALB biocatalysed synthesis of sulfoxides exploiting the dual role of AcOEt as solvent and reagent

A mild, chemoselective and sustainable biocatalysed synthesis of sulfoxides has been developed exploiting CALB and using AcOEt with a dual role of more environmentally friendly reaction solvent and enzyme substrate. A series of sulfoxides, including the drug omeprazole, have been synthesised in high yields and with excellent E-factors.

DABSO-based, three-component, one-pot sulfone synthesis

The addition of Grignard reagents or organolithium reagents to the SO 2-surrogate DABSO generates a diverse set of metal sulfinates, suitable for direct conversion to sulfone products. The metal sulfinates can be trapped in situ with a wide range of C-electrophiles, including alkyl, allyl, and benzyl halides, epoxides, and (hetero)aryliodoniums.

The epoxy-Ramberg-Baecklund reaction (ERBR): A sulfone-based method for the synthesis of allylic alcohols

The epoxy-Ramberg-Baecklund reaction (ERBR) is outlined, in which α,β-epoxy sulfones are converted into a range of mono-, di- and tri-substituted allylic alcohols, on treatment with base. Modification of this method enabled the preparation of enantio-enriched allylic alcohols following the diastereoselective epoxidation of enantio-enriched vinyl sulfones that were accessed efficiently from the chiral pool. The scope, optimisation and limitations of the ERBR as a method for the preparation of allylic alcohols are discussed. Wiley-VCH Verlag GmbH & Co. KGaA, 2006.