89922-58-7Relevant academic research and scientific papers
HETEROAROMATIC DERIVATIVE COMPOUND FOR ORGANIC ELECTROLUMINESCENT DEVICE AND ORGANIC ELECTROLUMINESCENT DEVICE COMPRISING THE SAME
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Paragraph 0234; 0241-0244, (2020/12/30)
A compound for an organic electroluminescent device comprises the compound 1. It is thereby possible. The present invention relates to a heterocyclic compound for an organic electroluminescent device and a method for manufacturing the same. Structural 1.
A phenothiazine dioxide derivatives of the preparation and use thereof
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, (2017/04/12)
The invention relates to a phenothiazine dioxide derivative and application thereof, belonging to the field of organic photoelectric materials. Phenothiazine is used as a parent body, and -SO2- is introduced to a molecular system, so that the favorable el
LIGHT-EMITTING MATERIAL FOR ORGANIC ELECTROLUMINESCENT DEVICE, ORGANIC ELECTROLUMINESCENT DEVICE USING SAME, AND MATERIAL FOR ORGANIC ELECTROLUMINESCENT DEVICE
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Paragraph 0350-0353, (2016/10/08)
Disclosed are a novel fused cyclic compound having excellent light emitting efficiency and thermal stability, a method for producing the same, and an organic electroluminescent device including the same compound. The fused cyclic compound is represented b
Bromination of 10-Phenylphenothiazine and 10-Phenylphenoxazine
Jovanovic, Misa V.,Biehl, Edward R.
, p. 1905 - 1908 (2007/10/02)
The reaction of either 10-phenylphenothiazine (1) with bromine in acetic acid or the cation radical of 1 with bromide ion gives ring substitution only and in accord with customary stoichiometry for nucleophilic substitution of aromatic cation radicals.However, the reaction of 1 with pyridinium bromide perbromide (2) gives predominantly 10-phenyl ring substitution and a small amount of ring substitution products.Evidence is presented which indicates that ring substitution occurs via cation radical whereas 10-phenyl substitution proceeds via electrophilic attack on the neutral molecule 1.Substitution of 10-phenylphenoxazine (4) occurs predominantly but not exclusively on the phenoxazine ring; some bromination does occur on the 10-phenyl ring.In contrast, the reaction of 4 with bromine gives only ring mono- and disubstitution products.These results indicate that both 1 and 4 react similarly under the same conditions.
