899431-70-0

Upstream product

• 67-64-1 acetone 
• 299409-44-2 N-benzyl-3-O-benzyl-5-deoxy-5-(hydroxylamino)-5-vinyl-1,2-O-isopropylidene-α-D-gluco-1,4-pentofuranoside 
• 299409-50-0 (R)-N-benzyl-1-((3aR,5R,6S,6aR)-6-(benzyloxy)-2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxol-5-yl)prop-2-en-1-amine 
• 162740-21-8 (Z)-N-benzyl-(3-O-benzyl-1,2-O-isopropylidene-α-D-xylofuranos-5-ylidene)amine N-oxide 
• 501-53-1 benzyl chloroformate 
• 899431-69-7 3-O-benzyl-1,2-O-isopropylidene-5,6,7-trideoxy-5-(N-benzyl-N-benzoxycarbonylamino)-α-D-gluco-6-eno-hepta-1,4-furanose 

Downstream Products

• 899431-87-9 Benzyl-[(R)-1-((3aR,5R,6S,6aR)-6-benzyloxy-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-2-hydroxy-but-3-enyl]-carbamic acid benzyl ester 
• 1383970-64-6 benzyl benzyl((R)-1-((3aR,5R,6S,6aR)-6-(benzyloxy)-2,2-dimethyltetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-2-hydroxyethyl)carbamate 
• 1383970-68-0 (2R,3R,4R,Z)-2-(benzylamino)-4-(benzyloxy)octadec-5-ene-1,3-diol 
• 1383970-67-9 (R)-3-benzyl-4-((1R,2R,Z)-2-(benzyloxy)-1-hydroxyhexadec-3-enyl)oxazolidin-2-one 
• 1383970-66-8 (R)-3-benzyl-4-((2R,3R,4R,5S)-3-(benzyloxy)-4,5-dihydroxytetrahydrofuran-2-yl)oxazolidin-2-one 
• 1383970-65-7 (R)-3-benzyl-4-((3aR,5R,6S,6aR)-6-(benzyloxy)-2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxol-5-yl)oxazolidin-2-one 
• 89955-60-2 1-epi-castanospermine 
• 79831-76-8 (1S,6S,7R,8R,8aR)-2,6,7,8-tetrahydroxy-indolizidine 
• 899431-79-9 (2R,3S)-1-Benzyl-3-benzyloxy-2-((3aR,5R,6S,6aR)-6-benzyloxy-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-pyrrolidine 
• 899431-71-1 (4R,5R)-3-Benzyl-4-((3aR,5R,6S,6aR)-6-benzyloxy-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-5-vinyl-oxazolidin-2-one 
• 899431-77-7 3-O-benzyl-1,2-O-isopropylidene-5,7,8-trideoxy-5-(N-benzylamino)-(5-N,6(S)-O-carbonyl)-α-L-glycero-D-gluco-7-eno-oct-1,4-furanose 
• 899431-73-3 (2R,3R)-1-Benzyl-2-((3aR,5R,6S,6aR)-6-benzyloxy-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-pyrrolidin-3-ol 
• 899431-78-8 (1R,2S)-1-Benzylamino-1-((3aR,5R,6S,6aR)-6-benzyloxy-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-but-3-en-2-ol 
• 899431-72-2 (1R,2R)-1-Benzylamino-1-((3aR,5R,6S,6aR)-6-benzyloxy-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-but-3-en-2-ol 

Relevant academic research and scientific papers

Total synthesis of the acetyl derivatives of lyxo-(2R,3R,4R)- phytosphingosine and (-)-jaspine B

The total synthesis of acetyl derivatives of lyxo-(2R,3R,4R)- phytosphingosine and (-)-jaspine B using a Grignard reaction on sugar-imine and a Wittig reaction as the key steps.

Intramolecular 5-endo-trig aminomercuration of β-hydroxy-γ- alkenylamines: Efficient route to a pyrrolidine ring and its application for the synthesis of (+)-castanospermine and analogues

The intramolecular aminomercuration reaction of sugar-derived β-hydroxy-γ-alkenylamines 8a-c undergoes 5-endo-trig cyclization in high yield. The sugar-substituted pyrrolidines thus obtained were elaborated to the synthesis of polyhydroxylated indolizidin