899694-59-8

Upstream product

• 2142-69-0 2-bromophenyl methyl ketone 
• 539-44-6 N-4-methylphenylhydrazine 
• 637-60-5 p-tolylhydrazine hydrochloride 
• 106-49-0 p-toluidine 

Downstream Products

• 1430808-97-1 10-methyl-6-propylindolo[1,2-c]quinazoline 
• 1385821-16-8 10-methyl-6-phenylindolo[1,2-c]quinazoline 
• 1385821-17-9 10-methyl-6-p-tolylindolo[1,2-c]quinazoline 
• 1430808-99-3 6-(4-fluorophenyl)-10-methylindolo[1,2-c]quinazoline 
• 1430809-00-9 10-methyl-6-(3-nitrophenyl)indolo[1,2-c]quinazoline 
• 1224635-42-0 8-methyl-6-phenyl-11H-benzo[a]carbazole 
• 1415639-66-5 8-chloro-6-phenyl-11H-benzo[a]carbazole 
• 1600518-89-5 C₁₆H₁₄BrN 
• 1469538-20-2 6-(4-chlorophenyl)-10-methylindolo[1,2-c]quinazoline 

Relevant academic research and scientific papers

Oxygenophilic Lewis Acid Promoted Synthesis of 2-Arylindoles from Anilines and Cyanoepoxides in Alcohol

A convenient synthetic method to indoles from anilines and cyanoepoxides was developed under the catalysis of BF3·OEt2 or AlCl3 in alcohols. The reaction involves a tandem reaction of the regiospecific ring-opening of cyanoepoxides with anilines, elimination of cyanide, intramolecular aromatic electrophilic substitution, and water elimination. The Lewis acid generated protic acid is an efficient catalyst. The method features readily accessible starting materials, wide substrate scope, transition-metal-free environment, and regiospecificity in the ring-opening of cyanoepoxides.

Direct Copper-Catalyzed C-3 Arylation of Diphenylphosphine Oxide Indoles

We have developed a simple and effective method for the C-3 arylation of phosphorus-containing indole compounds in the presence of CuI under mild conditions. This reaction provides a reliable method for the modification of ligands.

Preparation method of indole compounds

The invention provides a preparation method of indole compounds. 2-cyanoethylene oxide compounds and arylamine react under the catalysis effect of lewis acid (boron trifluoride diethyl etherate or aluminum trichloride) to obtain corresponding indole compo

Copper-catalyzed synthesis of benzocarbazoles via α-C-arylation of ketones

A simple and efficient copper-catalyzed method for the synthesis of 11H-benzo[a]carbazoles has been developed. The protocol uses readily available substituted 2-(2-bromophenyl)-1H-indoles and ketones as starting materials and an inexpensive catalyst system. The corresponding 11H-benzo[a]carbazoles were obtained in moderate to excellent yields. The Royal Society of Chemistry 2012..