89982-96-7

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 80510-04-9 1,2-bis(phosphino)benzene 
• 95-50-1 1,2-dichloro-benzene 
• 15104-46-8 1,2-bis(dimethoxyphosphoryl)benzene 

Downstream Products

• 128015-22-5 1-tert-Butyl-2-diphenylphosphanyl-1H-benzo[1,3]diphosphole 
• 128015-27-0 4a-t-Butyl-5-ethyl-1,4-diphenyl-4,4a-dihydro-1H-phosphorino-<1,2-a><1,3>benzodiphosphol 
• 128015-16-7 <2-Bis(trimethylsilyl)phosphino-phenyl>-<1-trimethylsiloxy-<2,4,6-tri(t-butyl)benzyliden>>-phosphin 
• 128015-12-3 C₁₃H₉P₂^(1-)*Li⁽¹⁺⁾ 
• 116631-72-2 P,P'-Dilithio-P,P'-bis-trimethylsilyl-1,2-diphosphinobenzen 

Relevant academic research and scientific papers

Synthesis and Structures of Dilithium (1,2-Diphosphido)benzenes

Treatment of the appropriate (1,2-diphosphino)benzenes C6H3(PHR)2-1,2-R'-4 (R'=Me or H; R=H, Ph or SiMe3) with LiBun and tmen in hexane afforded the dilithium diphosphides 2 (R'=H, R=Ph 1; R'=

A Dilithium o-Phenylenediphosphide 2 as a -)2-1,2> or 2-)2-1,2> Synthon: the X-Ray Structures of and (R = SiMe3, tmeda = 2)

The crystalline dilithium diphosphide 2 1 reacts with H2O, SiCl3Me, or to yield rac- and meso-C6H4(PHR)2-1,2, C6H4(PR2)2-1,2, or , respectively; whereas 1 with RR-Me2C(OCHCH2OTs)2 (Ts = toluene-p-sulfonate) or SiButCl3 affords or , respectively.