89986-79-8Relevant academic research and scientific papers
Direct conversion of sulfinamides to thiosulfonates without the use of additional redox agents under metal-free conditions
Ji, Yuan-Zhao,Li, Hui-Jing,Wang, Jun-Hu,Wu, Yan-Chao,Zhang, Chi
, p. 9291 - 9298 (2021/11/13)
Direct conversion of sulfinamides to thiosulfonates is described. Without the use of additional redox agents, the reaction proceeds smoothly in the presence of TFA under metal-free conditions. This protocol possesses many advantages such as odourless and stable starting materials, broad substrate scope, selective synthesis, and mild reaction conditions. This journal is
Mechanism in the chlorinolysis of sulfinyl chlorides
Ahern, Terence Patrick,Haley, Michael Francis,Langler, Richard Francis,Trenholm, June Ellen
, p. 610 - 614 (2007/10/02)
The successful synthesis and chlorinolysis of α-mercaptodimethyl sulfone have provided additional support for our contention that Pummerer rearrangements may occur during the chlorinolyses of α-sulfonyl sulfinyl chlorides.Further exploration of chlorinolyses of α-sulfonyl systems has uncovered the first observation of CS bond cleavage during the chlorinolyses of (i) a sulfinyl chloride and (ii) a sulfinate ester.
