35065-97-5Relevant articles and documents
Transition metal photoredox catalysis of radical thiol-ene reactions
Tyson, Elizabeth L.,Ament, Michael S.,Yoon, Tehshik P.
, p. 2046 - 2050 (2013/03/29)
We describe the anti-Markovnikov hydrothiolation of olefins using visible-light-absorbing transition metal photocatalysts. The key thiyl radical intermediates are generated upon quenching of photoexcited Ru*(bpz) 32 with a variety of thiols. The adducts of a wide variety of olefins and thiols are formed in excellent yield (73-99%).
An efficient one-pot synthesis of unsymmetrical ethers: A directly reductive deoxygenation of esters using an InBr3/Et3SiH catalytic system
Sakai, Norio,Moriya, Toshimitsu,Konakahara, Takeo
, p. 5920 - 5922 (2008/02/09)
(Chemical Equation Presented) This study describes a novel one-pot procedure for a directly reductive conversion of the carbonyl function of esters to the corresponding ethers by Et3SiH in the presence of a catalytic amount of InBr3.
Inhibition of human cytomegalovirus protease N(o) with monocyclic β- lactams
Deziel,Malenfant
, p. 1437 - 1442 (2007/10/03)
Monocyclic β-lactams have been identified as potent and selective inhibitors of the human cytomegalovirus protease (HCMV) N(o). Two series of these inhibitors are described, a peptidyl series of compounds and non- peptidic molecules featuring lower molecular weights. The SAR work that lead to the discovery of these inhibitors, together with their synthesis is also disclosed.
