89992-76-7

Upstream product

• 108-24-7 acetic anhydride 
• 115533-50-1 (-)-menthyl 4,6-O-benzylidene-2,3-O-carbonyl-β-D-mannopyranoside 
• 582-52-5 1,2:5,6-di-O-isopropylidene-α-D-glucofuranose 
• 115533-50-1 (3aS,4R,5aR,8R,9aR,9bS)-4-((1S,2R,5S)-2-Isopropyl-5-methyl-cyclohexyloxy)-8-phenyl-hexahydro-[1,3]dioxolo[4',5':4,5]pyrano[3,2-d][1,3]dioxin-2-one 
• 15356-60-2 (1S,2R,5S)-(+)-menthol 
• 115533-28-3 Phenyl-carbamic acid (2R,3R,4S,5R,6R)-2,3,5-trihydroxy-6-hydroxymethyl-tetrahydro-pyran-4-yl ester 
• 115533-37-4 Phenyl-carbamic acid (2R,3R,4S,5R,6R)-3,5-dihydroxy-2-hydroxymethyl-6-((1S,2R,5S)-2-isopropyl-5-methyl-cyclohexyloxy)-tetrahydro-pyran-4-yl ester 
• 34368-65-5 1,2-5,6-di-O-isopropylidene-3-O-(N-phenylcarbamoyl)-α-D-glucofuranose 
• 1125-88-8 benzaldehyde dimethyl acetal 
• 34368-66-6 1,2-O-isopropylidene-3-O-phenylcarbamoyl-α-D-glucofuranose 
• 115533-45-4 Trifluoro-methanesulfonic acid (2R,4aR,6R,7R,8S,8aR)-6-((1S,2R,5S)-2-isopropyl-5-methyl-cyclohexyloxy)-2-phenyl-8-phenylcarbamoyloxy-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yl ester 
• 115533-41-0 Phenyl-carbamic acid (2R,4aR,6R,7R,8R,8aR)-7-hydroxy-6-((1S,2R,5S)-2-isopropyl-5-methyl-cyclohexyloxy)-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-8-yl ester 
• 115533-31-8 (-)-menthyl 2,4,6-tri-O-acetyl-3-O-(N-phenylcarbamoyl)-β-D-glucopyranoside 
• 115533-29-4 1,2,4,6-tetra-O-acetyl-3-O-(N-phenylcarbamoyl)-β-D-glucopyranose 

Relevant academic research and scientific papers

Synthesis of β-D-mannosides from β-D-glucosides via an intramolecular SN2 reaction at C-2

The selective synthesis of β-D-mannosides was achieved by first synthesizing β-D-glucosides that carry an N-phenylcarbamoyl protecting group at O-3. These derivatives were transformed into the corresponding β-D-mannosides by intramolecular nucleophilic su