115559-99-4

Upstream product

• 582-52-5 1,2:5,6-di-O-isopropylidene-α-D-glucofuranose 
• 115533-28-3 3-O-(N-phenylcarbamoyl)-D-glucopyranose 
• 34368-66-6 1,2-O-isopropylidene-3-O-phenylcarbamoyl-α-D-glucofuranose 
• 115533-28-3 Phenyl-carbamic acid (2R,3R,4S,5R,6R)-2,3,5-trihydroxy-6-hydroxymethyl-tetrahydro-pyran-4-yl ester 
• 34368-65-5 1,2-5,6-di-O-isopropylidene-3-O-(N-phenylcarbamoyl)-α-D-glucofuranose 
• 103-71-9 phenyl isocyanate 
• 115533-29-4 1,2,4,6-tetra-O-acetyl-3-O-(N-phenylcarbamoyl)-β-D-glucopyranose 

Downstream Products

• 115533-33-0 methyl 6-O-<2,4,6-tri-O-acetyl-3-O-(N-phenylcarbamoyl)-β-D-glucopyranosyl>-2,3,4-tri-O-benzyl-α-D-glucopyranoside 
• 115533-32-9 methyl O-<2,4,6-tri-O-acetyl-3-O-(N-phenylcarbamoyl)-β-D-glucopyranosyl>-(1->4)-2,3,6-tri-O-benzyl-α-D-glucopyranoside 
• 115533-53-4 2-[(2S,3R,4R,5S,6R)-4-Benzyloxy-6-benzyloxymethyl-2-ethylsulfanyl-5-((3aS,4S,5aR,8R,9aR,9bS)-2-oxo-8-phenyl-hexahydro-[1,3]dioxolo[4',5':4,5]pyrano[3,2-d][1,3]dioxin-4-yloxy)-tetrahydro-pyran-3-yl]-isoindole-1,3-dione 
• 115533-37-4 Phenyl-carbamic acid (2R,3R,4S,5R,6R)-3,5-dihydroxy-2-hydroxymethyl-6-((1S,2R,5S)-2-isopropyl-5-methyl-cyclohexyloxy)-tetrahydro-pyran-4-yl ester 
• 142072-51-3 ethyl O-(2,3,4,6-tetra-O-acetyl-α-D-mannopyranosyl)-(1->3)-O-(2-O-acetyl-4,6-O-benzylidene-β-D-mannopyranosyl)-(1->4)-3,6-di-O-benzyl-2-deoxy-2-phthalimido-1-thio-β-D-glucopyranoside 
• 142072-52-4 ethyl O-(2,3,4,6-tetra-O-acetyl-α-D-mannopyranosyl)-(1->3)-O-(2-O-acetyl-β-D-mannopyranosyl)-(1->4)-3,6-di-O-benzyl-2-deoxy-2-phthalimido-1-thio-β-D-glucopyranoside 
• 115533-48-7 C₅₁H₄₉F₃N₂O₁₄S₂ 
• 115533-47-6 Trifluoro-methanesulfonic acid (4aR,6R,7R,8S,8aR)-2-phenyl-8-phenylcarbamoyloxy-6-((2R,3R,4S,5R,6S)-3,4,5-tris-benzyloxy-6-methoxy-tetrahydro-pyran-2-ylmethoxy)-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yl ester 
• 115533-46-5 Trifluoro-methanesulfonic acid (4aR,6R,7R,8S,8aR)-6-((2R,3R,4S,5R,6S)-4,5-bis-benzyloxy-2-benzyloxymethyl-6-methoxy-tetrahydro-pyran-3-yloxy)-2-phenyl-8-phenylcarbamoyloxy-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yl ester 
• 115533-44-3 ethyl O-<4,6-O-benzylidene-3-O-(N-phenylcarbamoyl)-β-D-glucopyranosyl>-(1->4)-3,6-di-O-benzyl-2-deoxy-2-phthalimido-1-thio-β-D-glucopyranoside 
• 115533-54-5 ethyl O-<4,6-O-benzylidene-2,3-O-(N-phenyliminocarbonyl)-β-D-mannopyranosyl>-(1->4)-3,6-di-O-benzyl-2-deoxy-2-phthalimido-1-thio-β-D-glucopyranoside 
• 142072-47-7 benzyl O-<4,6-O-(4-nitrobenzylidene)-3-O-(N-phenylcarbamoyl)-β-D-glucopyranosyl>-(1->4)-2-acetamido-3,6-di-O-benzyl-2-deoxy-α-D-glucopyranoside 
• 115533-53-4 ethyl O-(4,6-O-benzylidene-2,3-O-carbonyl-β-D-mannopyranosyl)-(1->4)-3,6-dibenzyl-2-deoxy-2-phthalimido-1-thio-β-D-glucopyranoside 
• 142072-50-2 ethyl O-(2-O-acetyl-4,6-O-benzylidene-β-D-mannopyranosyl)-(1->4)-3,6-di-O-benzyl-2-deoxy-2-phthalimido-1-thio-β-D-glucopyranoside 

Relevant academic research and scientific papers

Synthesis of β-D-mannosides from β-D-glucosides via an intramolecular SN2 reaction at C-2

The selective synthesis of β-D-mannosides was achieved by first synthesizing β-D-glucosides that carry an N-phenylcarbamoyl protecting group at O-3. These derivatives were transformed into the corresponding β-D-mannosides by intramolecular nucleophilic su