89998-72-1Relevant academic research and scientific papers
Acyclic Stereocontrol through Diastereo- and Enantioselective Sigmatropic Wittig Rearrangements
Tsai, David Jieh-Shyh,Midland, M.Mark
, p. 1842 - 1843 (1984)
High diastereoselection and complete transfer of chirality is observed in the Wittig rearrangements of optically active allyl (Z)-2-methylhex-4-en-3-yl ether.The acyclic stereoselection in the Wittig rearrangement of other (E)- and (Z)-allylic ethers is also examined.
