Acyclic Stereocontrol through Diastereo- and Enantioselective Sigmatropic Wittig Rearrangements

DOI: 10.1021/jo00184a040

Source and publish data:

Journal of Organic Chemistry p. 1842 - 1843 (1984)

Update date:2022-08-05

Topics: Enantioselective Diastereoselective

Authors:

Tsai, David Jieh-Shyh

Midland, M.Mark

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Article abstract of DOI:10.1021/jo00184a040

High diastereoselection and complete transfer of chirality is observed in the <2,3> Wittig rearrangements of optically active allyl (Z)-2-methylhex-4-en-3-yl ether.The acyclic stereoselection in the <2,3> Wittig rearrangement of other (E)- and (Z)-allylic ethers is also examined.

Full text of DOI:10.1021/jo00184a040

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