89998-78-7Relevant academic research and scientific papers
Hochstereoselektive Allylierung von Benzaldehyd: Bildung einer Allylzink-Spezies mit definierter Konfiguration aus einer ?-Allylpalladium-Zwischenstufe und Diethylzink
Tamaru, Yoshinao,Tanaka, Akihiro,Yasui, Kengo,Goto, Sachio,Tanaka, Shuji
, p. 862 - 864 (2007/10/02)
Stichworte: Allylierungen * ?-Allylpalladiumverbindungen * Umpolungen * Zinkverbindungen
Acyclic Stereocontrol through Diastereo- and Enantioselective Sigmatropic Wittig Rearrangements
Tsai, David Jieh-Shyh,Midland, M.Mark
, p. 1842 - 1843 (2007/10/02)
High diastereoselection and complete transfer of chirality is observed in the Wittig rearrangements of optically active allyl (Z)-2-methylhex-4-en-3-yl ether.The acyclic stereoselection in the Wittig rearrangement of other (E)- and (Z)-allylic ethers is also examined.
