9003-63-8

Basic information

• Product Name: POLY(N-BUTYL METHACRYLATE)
• Synonyms: 2-Propenoicacid,2-methyl-,butylester,homopolymer;Butyl2-methyl-2-propenoate,homopolymer;butyl2-methyl-2-propenoatehomopolymer;Butylmethacrylatehomopolymer;methacrylicacid,butylester,polymers;Methacrylicacid,butylesterhomopolymer;N-BUTYL METHACRYLATE (POLYMER);N-BUTYL METHACRYLATE RESIN
• CAS NO: 9003-63-8
• Molecular Formula: (C10H20O2)n
• Molecular Weight: 142.2
• EINECS: 202-615-1
• Product Categories: Hydrophobic Polymers;Methacrylate PolymersSelf Assembly&Contact Printing;PMMA-Based Resins;Stamps for Nanoprint Lithography&Microcontact Printing;Poly(butyl methacrylate);Alphabetic;Organic Soluble Polymers;P;POLB - POLYPolymer Standards;Polymers;Acrylics;Methacrylate Polymers;Microcontact Printing;PMMA-Based Resins;Stamps for Nanoprint Lithography &Contact Printing;Hydrophobic Polymers;Materials Science;Micro/NanoElectronics;Polymer Science;Self Assembly &
• Mol File: 9003-63-8.mol
• Article Data: 29

Chemical Properties

• Boiling Point: 160°Cat760mmHg
• Flash Point: 50.6°C
• Appearance: /powder
• Density: 1.07 g/mL at 25 °C(lit.)
• Vapor Pressure: 2.44mmHg at 25°C
• Refractive Index: n20/D 1.483
• CAS DataBase Reference: POLY(N-BUTYL METHACRYLATE)(CAS DataBase Reference)
• NIST Chemistry Reference: POLY(N-BUTYL METHACRYLATE)(9003-63-8)
• EPA Substance Registry System: POLY(N-BUTYL METHACRYLATE)(9003-63-8)

Safety Data

• Hazard Codes: Xi
• Statements: 10-36/37/38-43
• Safety Statements: 24/25
• WGK Germany: 1
• RTECS: UD3399000
• Hazardous Substances Data: 9003-63-8(Hazardous Substances Data)

Usage

Uses

It may be used to study the photoluminescence in EuTFC embedded in Poly(butyl methacrylate) (PBMA) polymer films.

Definition

ChEBI: A macromolecule composed of repeating butyl isobutyrate units.

InChI:InChI=1/C8H14O2/c1-4-5-6-10-8(9)7(2)3/h2,4-6H2,1,3H3

Upstream product

• 816-50-2 α-hydroxy-isobutyric acid butyl ester 
• 348603-27-0 α-isopropoxy-isobutyric acid butyl ester 
• 188897-40-7 α-butoxy-isobutyric acid butyl ester 
• 75-86-5 2-hydroxy-2-methylpropanenitrile 
• 80-62-6 methacrylic acid methyl ester 
• 71-36-3 butan-1-ol 
• 79-41-4 poly(methacrylic acid) 
• 17860-04-7 2-isopropoxy-2-methylpropanoic acid 
• 7790-94-5 chlorosulfonic acid 
• 92-84-2 10H-phenothiazine 
• 13499-05-3 hafnium tetrachloride 
• 123-54-6 acetylacetone 
• 594-61-6 2-methyllactic acid 
• 463-49-0 1,2-propanediene 

Downstream Products

• 58911-06-1 1,4-dimethyl-cyclohex-3-enecarboxylic acid butyl ester 
• 100267-39-8 Isopropylphosphonsaeure-O,O-dibenzylester-butylester 
• 100210-87-5 Isopropylphosphonsaeure-butylester-dicyclohexylester 
• 1447813-75-3 butyl (R)-4-(4-chlorophenyl)-2-methyl-4-oxobutanoate 
• 4254-20-0 4,4'-dichlorobenzoin 
• 1609585-03-6 (E)-butyl 5-(4-cyanophenyl)-2-methylpent-4-enoate 
• 1609585-04-7 (E)-butyl 5-(4-cyanophenyl)-2-methylpent-2-enoate 
• 1620079-51-7 butyl 2-methyl-4-(methyl(phenyl)amino)butanoate 
• 1638610-40-8 butyl 3-(2-benzoylbenzofuran-3-yl)-2-methylpropanoate 
• 1608454-65-4 C₂₈H₃₀N₃O₂⁽¹⁺⁾*Cl^(1-) 
• 1608454-60-9 5-(2-cyanopropyl)-1,3,4-triphenyl-4H-1,2,4-triazol-1-ium chloride 
• 1402975-26-1 (E)-butyl 3-(3,5-dimethylphenyl)-2-methylacrylate 
• 1402975-32-9 butyl 2-(3,5-dimethylbenzyl)acrylate 
• 1402975-27-2 (E)-butyl 3-(3,4-dimethylphenyl)-2-methylacrylate 

Relevant articles and documents

An efficient, practical and cost-effective polymer-supported catalyst for the transesterification of methyl methacrylate by 1-butanol

A straightforward and cost-effective synthesis of a polymer-supported titanium alkoxide catalyst is reported. The described synthesis involves cheap, readily available and relatively non toxic chemicals, solvents and workup procedures. Efficiency and stability of the catalyst were tested in a laboratory-scale continuous flow reactor under equilibrium conditions over a month period. The average daily titanium leaching was estimated to less than 1% of the total amount of titanium engaged. To our knowledge, this result is the best obtained, to date, concerning the use of heterogeneous titanate for the catalysis of transesterification reactions.

Silica-Supported MnII Sites as Efficient Catalysts for Carbonyl Hydroboration, Hydrosilylation, and Transesterification

Manganese, the third most abundant transition-metal element after iron and titanium, has recently been demonstrated to be an effective homogeneous catalyst in numerous reactions. Herein, the preparation of silica-supported MnII sites is reported using Surface Organometallic Chemistry (SOMC), combined with tailored thermolytic molecular precursors approach based on Mn2[OSi(OtBu)3]4 and Mn{N(SiMe3)2}2?THF. These supported MnII sites, free of organic ligands, efficiently catalyze numerous reactions: hydroboration and hydrosilylation of ketones and aldehydes as well as the transesterification of industrially relevant substrates.

METHOD FOR THE PRODUCTION PROCESS OF BUTYL METHACRYLATE

The present invention relates to a preparation method of butyl methacrylate, which comprises the steps of: a) preparing butyl methacrylate through ester exchange reaction of n-butanol and methyl methacrylate in the presence of titanium tetrabutoxide catalyst; and b) removing the catalyst by adding glycerol to butyl methacrylate after the ester exchange reaction. The preparation method of butyl methacrylate in the present invention improves removal rate of residual solvents remaining after recovering the products after the ester exchange reaction, and has the catalyst removal process at low costs.COPYRIGHT KIPO 2016