19471-47-7

Upstream product

• 7647-01-0 hydrogenchloride 

Downstream Products

• 91-20-3 naphthalene 
• 69547-16-6 ethylenebis(trimethylphosphine)platinum 
• 90065-11-5 trans-chloro-bis(trimethylphosphine)(phenyl)platinum(II) 
• 111112-89-1 {(allyl)bis(trimethylphosphine)platinum} tetraphenylborate 
• 75982-99-9 (diphenylacetylene)bis(trimethylphosphine)platinum⁽⁰⁾ 
• 111112-81-3 cis-hydrido-platinum(II)(triphenylSi)bis(trimethylphosphine) 
• 111112-80-2 cis,trans,cis-bishydrido-platinum(IV)(triphenylGe)2bis(trimethylphosphine) 
• 111112-82-4 cis,trans,cis-bishydrido-platinum(II)(triphenylSn)2 bis(trimethylphosphine) 
• 151264-36-7 {PtCl(P(CH₃)3)((C₆H₅)2PNHP(C₆H₅)2)}⁽¹⁺⁾*Cl^(1-)={PtCl(P(CH₃)3)((C₆H₅)2PNHP(C₆H₅)2)}Cl 
• 300772-90-1 cis-[PtCl(2-(diphenylphosphinoamino)pyridine-P,N)(PMe₃)]Cl 
• 192936-52-0 trans-[PtBr(C₆Cl₅)(PMe₃)2] 
• 816419-05-3 trans-Pt(II)Cl(trimethylphosphine)2(CCC₆H₅) 
• 952489-23-5 bis(triethylphosphine)gold(I) hexafluorophosphate 
• 192936-50-8 [(PMe3)2(C6Cl5)Pt(μ-H)Pt(C6Cl5)(PMe3)2](CF3SO3) 

Relevant academic research and scientific papers

Cyclic Platina(borasiloxane)s and Platina(siloxane)s and Their Chemical Properties

[Pt(SiHPh2)2(dmpe)] (dmpe = 1,2-bis(dimethylphosphino)ethane) reacts with arylboronic acids to produce six-membered platinacycles [Pt(SiPh2-O-BAr-O-SiPh2)(dmpe)] (Ar = C6H4-4-COMe (1a), C6H4-4-CF3 (1b)). X-ray crystallography of 1a revealed the structure having a planar six-membered ring, composed of Pt, O, B, and Si atoms. Reaction of H2O with [Pt(SiHPh2)2(dmpe)] formed a four-membered cyclic complex, [Pt(SiPh2-O-SiPh2)(dmpe)] (2), which was observed in the initial reaction mixture of 4-acetylphenylboronic acid with [Pt(SiHPh2)2(dmpe)]. Exposure of solutions of [Pt(SiHPh2)2(dmpe)] and of [Pt(SiHAr2)2(PMe3)2] (Ar = Ph, C6H4-4-Me) to air resulted in the formation of the cyclic platina(siloxane)s, [Pt(O-SiPh2-O-SiPh2-O)(dmpe)] (3) and [Pt(O-SiAr2-O-SiAr2-O)(PMe3)2] (4: Ar = Ph; 5: Ar = C6H4-4-Me), respectively. The six-membered platina(borasiloxane) 1a reacts with H2GePh2 and with CF3CO2H to release the cyclic borasiloxanes as the products. The former reaction affords [Pt(GeHPh2)2(dmpe)], while the latter produces [Pt(OCOCF3)2(dmpe)] as the Pt-containing products. A similar reaction of HCl with platina(siloxane) 4 gives a disiloxanediol via cleavage of the Pt-O bonds. Complex 4 reacts with H2SiPh2 to form a triplatinum complex, [{Pt(PMe3)}3(μ-SiPh2)3] (15), which is obtained under milder conditions than the previously reported reaction starting from [Pt(SiHPh2)2(PMe3)2].