901130-15-2Relevant academic research and scientific papers
Dynamic thermodynamic resolution: Solvent effects, mechanism, and an asymmetric 3,4,5-substituted benzazepine synthesis
Park, Yong Sun,Yum, Eul Kgun,Basu, Amit,Beak, Peter
, p. 2667 - 2670 (2007/10/03)
The resolution in the lithiation-substitution sequence from 1 to 4-11 in MTBE is shown to be under thermodynamic control in contrast to the previous report of kinetic control in diethyl ether. Diastereomeric equilibration of a soluble complex is shown to
