90128-95-3

Basic information

• Product Name: (-)-(2S,2'R)-2-(methoxymethyl)-1-<(2'-methyl-3'-phenyl)propylideneamino>pyrrolidine
• Synonyms: (-)-(2S,2'R)-2-(methoxymethyl)-1-<(2'-methyl-3'-phenyl)propylideneamino>pyrrolidine
• CAS NO: 90128-95-3
• Molecular Weight: 260.379
• Mol File: 90128-95-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (-)-(2S,2'R)-2-(methoxymethyl)-1-<(2'-methyl-3'-phenyl)propylideneamino>pyrrolidine(CAS DataBase Reference)
• NIST Chemistry Reference: (-)-(2S,2'R)-2-(methoxymethyl)-1-<(2'-methyl-3'-phenyl)propylideneamino>pyrrolidine(90128-95-3)
• EPA Substance Registry System: (-)-(2S,2'R)-2-(methoxymethyl)-1-<(2'-methyl-3'-phenyl)propylideneamino>pyrrolidine(90128-95-3)

Safety Data

• Hazardous Substances Data: 90128-95-3(Hazardous Substances Data)

Upstream product

• 72203-94-2 N-[(S)-2-methoxymethylpyrrolidin-1-yl]propan-1-imine 
• 100-39-0 benzyl bromide 
• 59983-39-0 (S)-1-amino-2-(methoxymethyl)pyrrolidine 

Downstream Products

• 89999-56-4 (R)-2-Methyl-3-phenyl-propylamine 
• 89999-55-3 (S)-2-Methyl-3-phenyl-propylamine 
• 63126-47-6 (2S)-2-(methoxymethyl)-1-pyrrolidine 
• 192054-80-1 ((S)-2-Methoxymethyl-pyrrolidin-1-yl)-((1S,2R)-2-methyl-1,3-diphenyl-propyl)-amine 
• 192054-77-6 ((S)-2-Methoxymethyl-pyrrolidin-1-yl)-[(R)-1-((R)-1-methyl-2-phenyl-ethyl)-pentyl]-amine 

Relevant articles and documents

Asymmetric synthesis of primary amines by nucleophilic addition of alkyllithium compounds to aldehyde SAMP/RAMP hydrazones

The aldehydes 1 or 5 are converted to the SAMP hydrazones 2 or the α-alkylated SAMP hydrazones 7 and treated with organolithium compounds at low temperature. Cleavage of the N-N bond of the resulting hydrazines 3 and 8 with Raney-Ni/H2, or of t