90133-93-0

Upstream product

• 542-69-8 1-iodo-butane 
• 540-37-4 p-aminoiodobenzene 
• 613-29-6 N-Dibutylaniline 
• 53358-54-6 1-bromo-4-(N,N-dibutyl)aniline 
• 109-65-9 1-bromo-butane 

Downstream Products

• 90134-06-8 (E)-{4-[2-(4-bromophenyl)vinyl]phenyl}dibutylamine 
• 435268-50-1 4-{{4-{[4-(dibutylamino)phenyl]ethynyl}-2,5-bis(octyloxy)phenyl}ethynyl}-2,5-bis(octyloxy)benzaldehyde 
• 435268-51-2 4-{{4-{{4-{[4-(dibutylamino)phenyl]ethynyl}-2,5-bis(octyloxy)phenyl}ethynyl}-2,5-bis(octyloxy)phenyl}ethynyl}-2,5-bis(ocyloxy)benzaldehyde 
• 41876-68-0 (4-di-n-butylamino)phenylacetylene 
• 1044502-87-5 C₂₃H₂₉N 
• 1198163-12-0 4,4'-(1,4-phenylenebis(ethyne-2,1-diyl))bis(N,N-dibutylaniline) 
• 1197154-84-9 C₂₁H₂₈N₂ 
• 90133-94-1 trans-4-pyridine 
• 1253385-70-4 N,N-dibutyl-4-((triisopropylsilyl)ethynyl)aniline 
• 1253385-65-7 1,6-bis(4-(dibutylamino)phenyl)hexa-1,5-diyne-3,4-dione 
• 398469-94-8 p-(dibutylamino)benzonitrile 
• 1421061-30-4 [5,15-bis(3,5-dioctyloxyphenyl)-10,20-bis[4-(N,N-dibutylamino)phenylethynyl]porphyrinato]zinc(II) 
• 1424266-32-9 C₁₀₀H₁₄₃N₅O₄SiZn 
• 613-29-6 N-Dibutylaniline 

Relevant academic research and scientific papers

New Aggregation-Induced Emitters: Tetraphenyldistyrylbenzenes

The synthesis of five novel distyrylbenzene (DSB) derivatives, featuring a central tetraphenylbenzene core, is reported. The targets show aggregation-induced emission (AIE), which, however, is substituent-dependent. For the pure hydrocarbon and derivative

Application of double click to prepare near-infrared absorbing dye for photo-thermal tuning of cholesteric liquid crystal

Cholesteric liquid crystal (CLC) exhibits selective reflection, making it a great application in the field of light control. Here, a near-infrared light (NIR) was used to drive the self-organizing spiral superstructure of the cholesteric liquid crystal to

Charge transfer NIR dyes for improved photoacoustic effect

A new class of NIR absorbing dyes accessed by a cycloaddition-cycloreversion reaction of alkynes with 2,3,5,6-tetrafluoro-7,7,8,8-tetracyanoquinodimethane is reported. The photoacoustic effect of the new NIR dyes was systematically studied. The results va

Nonlinear optical and energy-level modulation of organic alkynes by click chemistry

A series of novel donor–acceptor chromophores have been successfully synthesized in excellent yield by metal-free [2+2] click chemistry, which was effective in the energy-level modulation of organic the π-conjugation aniline derivatives. Meanwhile, struct

In vitro imaging of β-cells using fluorescent cubic bicontinuous liquid crystalline nanoparticles

To evaluate the potential of monoolein-based cubic bicontinuous liquid crystalline nanoparticles (cubosomes) as diagnostic tools in diabetes and pancreatic β-cell transplantation, fluorescent cubosomes were formulated, entrapping within the lipid bilayer a newly synthesized, potent, hydrophobic dye. Cryo-TEM, SAXS, and DLS were performed to assess the morphological and structural aspects of this formulation. Rat pancreatic β-cells (INS-1E) readily took up the cubosome nanoparticles, as revealed by in vitro internalization tests, and flow-cytometric analyses confirmed the persistence of the fluorescence for up to 24 hours. The cytotoxicity of cubosomes at various concentrations, evaluated with a real-time analysis of proliferation, revealed that the proliferation curves relative to the less concentrated formulation (5 μM in terms of monoolein content) were comparable to the untreated cultures. INS-1E cell cycle and apoptosis supported such results. In conclusion, this formulation, with dye content in the nanomolar range, seems to be useful for β-cell imaging.

Enhanced electro-optic activity from the triarylaminophenyl-based chromophores by introducing heteroatoms to the donor

A series of chromophores T1-T3 based on the same thiophene π-conjugation and tricyanofuran acceptor (TCF) but with different heteroatoms in the triarylaminophenyl (TAA) donors have been synthesized and systematically investigated in this study. Density functional theory (DFT) was used to calculate the HOMO-LUMO energy gaps and first-order hyperpolarizability (β) of these chromophores. Moreover, to determine the redox properties of these chromophores, cyclic voltammetry (CV) experiments were performed. After introducing the heteroatom to the benzene ring of the TAA donor, reduced energy gaps of 1.28 and 0.84 eV were obtained for chromophores T2 and T3, respectively, which was much lower than for chromophore T1 (ΔE = 1.46 eV). These chromophores showed excellent thermal stability with their decomposition temperatures all above 280 °C. Compared with results obtained from the chromophore without the heteroatom (T1), these new chromophores show better intramolecular charge-transfer (ICT) absorption. Most importantly, the high molecular hyperpolarizability (β) of these chromophores can be effectively translated into large electro-optic (EO) coefficients (r33) in the poled polymers. The electro-optic coefficient of poled films containing 25 wt% of these new chromophores doped in amorphous polycarbonate (APC) afforded values of 16, 58 and 95 pm V-1 at 1310 nm for chromophores T1-T3, respectively. High r33 values indicated that introducing heteroatom to the benzene ring of the TAA donor can efficiently improve the electron-donating ability, which improves the hyperpolarizability (β). The long-chain on the benzene ring of the TAA donor, acting as the isolation group, may reduce intermolecular electrostatic interactions, thus enhancing the macroscopic EO activity. These properties, together with the good solubility, suggest the potential use of these new chromophores as advanced material devices. This journal is

Synthesis, characterization and DFT calculations of new ethynyl-bridged C60 derivatives

A new series of soluble C60 derivatives for organic electronic application has been synthesized by ethynylation reaction using different electron-donating and electron-withdrawing groups of varying length.

Photochromic dichroic naphtho-pyrans and optical articles containing them

A naphthopyran compound represented by the formulae (I) to (IV) wherein : ■ m1, m2, p, q are each an integer comprised from 0 to 4 or 5 inclusive; ■ R1, R2 and R4, represent a group selected from halogen, H, -Ra, aryl, -OH, -ORa, -SH, -SRa, -NH2, -NRaRa1, -NRbRc, -NRa1CORa, -NRa1CO(aryl), -NRa1aryl, -N-aryl2, -N(aryl)CO(aryl), -CO-Ra, -CO2Ra1, -OC(O)-Rd, and - X-(Re)-Y, and linear or branched (C1-C18) perfluoroalkyl group, wherein Ra, Ra1, Rb, Rc, X, Y, Re, Rd are as defined into the description; ■ Z1 represent a group selected from: wherein R3, J and n are as defined into the description; ■ R5, Z2, Z3 are as defined into the description; ■ Z4 represent a group selected from: o wherein R3, J and n are as defined hereinbefore; ■ with the provision that for compounds of formula (II) when Z1 represents a group then Z3 is not a hydrogen.

NONLINEAR OPTICAL MATERIAL COMPOSITION AND METHOD OF MANUFACTURE

Embodiments of the present disclosure provide non-linear optical compounds and compositions comprising a silole-derivative. In an embodiment, the silole derivative comprises a chromophore including a structure represented by Formula (A): wherein each Of R

Donor-substituted perethynylated dehydroannulenes and radiaannulenes: Acetylenic carbon sheets featuring intense intramolecular charge transfer

In this article, we report the preparation of unprecedented φ-conjugated macrocycles (Fig. 1) by acetylenic scaffolding using modular tetraethynylethene (TEE, 3,4-diethynylhex-3-ene-1,5-diyne) building blocks. A novel photochemical access to (Z)-bisdeprot